Glycolysis of polyurethane foams and elastomers

被引:100
作者
Borda, J [1 ]
Pásztor, G [1 ]
Zsuga, M [1 ]
机构
[1] Univ Debrecen, Dept Appl Chem, H-4010 Debrecen 10, Hungary
基金
匈牙利科学研究基金会;
关键词
glycolysis; polyurethane; foam; elastomer; reaction mechanism;
D O I
10.1016/S0141-3910(00)00030-6
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Optimum conditions for the glycolysis of polyurethane flexible foams and elastomers are reported. The crude, two-phase liquid reaction mixture was separated and the upper phase was used as the polyol component of an industrial adhesive mixture. During glycolysis the formation of carbon dioxide was recognized and quantified. On the basis of this new finding a novel reaction mechanism is proposed for the glycolysis of polyurethanes. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:419 / 422
页数:4
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