Multiple conformational changes of β-tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

被引：48
作者：
Koide, Taro [1 ]
Youfu, Katsuyuki [1 ]
Saito, Shohei [1 ]
Osuka, Atsuhiro [1 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 40期
关键词：
EXPANDED PORPHYRINS; MOBIUS AROMATICITY; METAL-COMPLEXES; CHEMISTRY; HEXAPHYRINS; MOLECULES;
D O I：
10.1039/b910167e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
beta-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28] hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Mobius aromaticity.
引用
收藏
页码：6047 / 6049
页数：3
相关论文
共 34 条
  • [11] Heterobismetal complexes of [26]hexaphyrin(1.1.1.1.1.1)
    Mori, Shigeki
    Osuka, Atsuhiro
    [J]. INORGANIC CHEMISTRY, 2008, 47 (10) : 3937 - 3939
  • [12] Peripheral fabrications of a bis-gold(III) complex of [26]hexaphyrin(1.1.1.1.1.1) and aromatic versus antiaromatic effect on two-photon absorption cross section
    Mori, Shigeki
    Kim, Kil Suk
    Yoon, Zin Seok
    Noh, Su Bum
    Kim, Dongho
    Osuka, Atsuhiro
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (37) : 11344 - +
  • [13] Group 12 metal complexes of [26]hexaphyrin(1.1.1.1.1.1)
    Mori, Shigeki
    Shimizu, Soji
    Shin, Ji-Young
    Osuka, Atsuhiro
    [J]. INORGANIC CHEMISTRY, 2007, 46 (11) : 4374 - 4376
  • [14] meso-substituted expanded porphyrins:: new and stable hexaphyrins
    Neves, MGPMS
    Martins, RM
    Tomé, AC
    Silvestre, AJD
    Silva, AMS
    Félix, V
    Drew, MGB
    Cavaleiro, JAS
    [J]. CHEMICAL COMMUNICATIONS, 1999, (04) : 385 - 386
  • [15] Lemniscular hexaphyrins as examples of aromatic and antiaromatic double-twist Mobius molecules
    Rzepa, Henry S.
    [J]. ORGANIC LETTERS, 2008, 10 (05) : 949 - 952
  • [16] Mobius aromaticity and delocalization
    Rzepa, HS
    [J]. CHEMICAL REVIEWS, 2005, 105 (10) : 3697 - 3715
  • [17] N-fusion reaction sequence of heptaphyrin(1.1.1.1.1.1.1): Singly, doubly, and quadruply N-fused heptaphyrins
    Saito, Shohei
    Osuka, Atsuhiro
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (35) : 9095 - 9102
  • [18] Protonation-Triggered Conformational Changes to Mobius Aromatic [32]Heptaphyrins(1.1.1.1.1.1.1)
    Saito, Shohei
    Shin, Jae-Yoon
    Lim, Jong Min
    Kim, Kil Suk
    Kim, Dongho
    Osuka, Atsuhiro
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (50) : 9657 - 9660
  • [19] Unambiguous identification of Mobius aromaticity for meso-Aryl-substituted [28]hexaphyrins(1.1.1.1.1.1)
    Sankar, Jeyaraman
    Mori, Shigeki
    Saito, Shohei
    Rath, Harapriya
    Suzuki, Masaaki
    Inokuma, Yasuhide
    Shinokubo, Hiroshi
    Kim, Kil Suk
    Yoon, Zin Seok
    Shin, Jae-Yoon
    Lim, Jong Min
    Matsuzaki, Yoichi
    Matsushita, Osamu
    Muranaka, Atsuya
    Kobayashi, Nagao
    Kim, Dongho
    Osuka, Atsuhiro
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (41) : 13568 - 13579
  • [20] Synthetic expanded porphyrin chemistry
    Sessler, JL
    Seidel, D
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (42) : 5134 - 5175
1234