Multiple conformational changes of β-tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26] and [28]hexaphyrins(1.1.1.1.1.1)

被引：48

作者：

Koide, Taro ^{[1
]}

Youfu, Katsuyuki ^{[1
]}

Saito, Shohei ^{[1
]}

Osuka, Atsuhiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 40期

关键词：

EXPANDED PORPHYRINS; MOBIUS AROMATICITY; METAL-COMPLEXES; CHEMISTRY; HEXAPHYRINS; MOLECULES;

D O I：

10.1039/b910167e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

beta-Tetraphenyl meso-hexakis(pentafluorophenyl) substituted [26]hexaphyrin 3 is conformationally flexible between rectangular and figure-of-eight shapes and its two-electron reduced [28] hexaphyrin 4 takes figure-of-eight conformations, which are changed, upon protonation, to twisted conformations with distinct Mobius aromaticity.

引用

页码：6047 / 6049

页数：3

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