Synergistic Effects of Fe2O3 with Layered Double Hydroxides in EVA/LDH Composites

被引：49
作者：
Jiao, Chuanmei [1 ]
Chen, Xilei [1 ]
Zhang, Jun [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Peoples R China
来源：
JOURNAL OF FIRE SCIENCES | 2009年 / 27卷 / 05期
基金：
中国国家自然科学基金;
关键词：
synergistic effect; layered double hydroxide; halogen-free flame retardant; FLAME-RETARDANT MECHANISM; VINYL ACETATE COPOLYMER; MAGNESIUM-HYDROXIDE; FIRE RETARDANCY; POLYMER NANOCOMPOSITES; AMMONIUM POLYPHOSPHATE; CROSS-LINKING; EVA BLENDS; FE-MMT; FLAMMABILITY;
D O I：
10.1177/0734904109102033
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The synergistic effects of Fe2O3 with layered double hydroxides (LDH) in ethylene vinyl acetate copolymer/LDH (EVA/LDH) composites have been studied using limiting oxygen index (LOI), UL-94 tests, and cone calorimeter test (CCT). The results from the LOI and UL-94 tests show that the Fe2O3 can also act as flame retardant synergistic agents in the EVA/LDH composites. The CCT data indicated that the addition of Fe2O3 in the EVA/LDH system can greatly reduce the heat release rate, total heat release, carbon monoxide and carbon dioxide.
引用
收藏
页码：465 / 479
页数：15
相关论文
共 25 条
[1]   Effect of fillers on the fire retardancy of intumescent polypropylene compounds [J].
Almeras, X ;
Le Bras, M ;
Hornsby, P ;
Bourbigot, S ;
Marosi, G ;
Keszei, S ;
Poutch, F .
POLYMER DEGRADATION AND STABILITY, 2003, 82 (02) :325-331
[2]   Catalyzing carbonization function of ferric chloride based on acrylonitrile-butadiene-styrene copolymer/organophilic montmorillonite nanocomposites [J].
Cai, Yibing ;
Hu, Yuan ;
Song, Lei ;
Xuan, Shanyong ;
Zhang, Yi ;
Chen, Zuyao ;
Fan, Weichen .
POLYMER DEGRADATION AND STABILITY, 2007, 92 (03) :490-496
[3]   Effects of tin additives on the flammability and smoke emission characteristics of halogen-free ethylene-vinyl acetate copolymer [J].
Cross, MS ;
Cusack, PA ;
Hornsby, PR .
POLYMER DEGRADATION AND STABILITY, 2003, 79 (02) :309-318
[4]  
[冯桃 Feng Tao], 2003, [应用化学, Chinese Journal of Applied Chemistry], V20, P117
[5]   Synergistic flame retardant mechanism of fumed silica in ethylene-vinyl acetate/magnesium hydroxide blends [J].
Fu, MZ ;
Qu, BJ .
POLYMER DEGRADATION AND STABILITY, 2004, 85 (01) :633-639
[6]   Flammability parameters of wood tested on a cone calorimeter [J].
Grexa, O ;
Lübke, H .
POLYMER DEGRADATION AND STABILITY, 2001, 74 (03) :427-432
[7]   Irradiation crosslinking and halogen-free flame retardation of EVA using hydrotalcite and red phosphorus [J].
Jiao, CM ;
Wang, ZZ ;
Chen, XL ;
Yu, BY ;
Hu, Y .
RADIATION PHYSICS AND CHEMISTRY, 2006, 75 (05) :557-563
[8]   Flame retardation of ethylene-vinyl acetate copolymer using nano magnesium hydroxide and nano hydrotalcite [J].
Jiao, CM ;
Wang, ZZ ;
Ye, Z ;
Hu, Y ;
Fan, WC .
JOURNAL OF FIRE SCIENCES, 2006, 24 (01) :47-64
[9]   Synthesis and properties of poly(methyl methacrylate)/clay nanocomposites using natural montmorillonite and synthetic Fe-montmorillonite by emulsion polymerization [J].
Kong, QH ;
Hu, Y ;
Yang, L ;
Fan, WC ;
Chen, ZY .
POLYMER COMPOSITES, 2006, 27 (01) :49-54
[10]   Influence of Fe-MMT on crosslinking and thermal degradation in silicone rubber/clay nanocomposites [J].
Kong, Qinghong ;
Hu, Yuan ;
Song, Lei ;
Wang, Yinling ;
Chen, Zuyao ;
Fan, Weicheng .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2006, 17 (06) :463-467
123