The effect of temperature on the solubility of benzoic acid derivatives in water

被引：37

作者：

Jia Qing-Zhu ^{[1
]}

Ma Pei-Sheng

Zhou Huan

Xia Shu-Qian

Wang Qiang

Qiao Yan

机构：

[1] Tianjin Univ, Coll Chem Engn, Tianjin 300072, Peoples R China

[2] Tianjin Univ Sci & Technol, Coll Marine Sci & Engn, Tianjin 300457, Peoples R China

来源：

FLUID PHASE EQUILIBRIA | 2006年 / 250卷 / 1-2期

关键词：

o-nitro-benzoic acid; p-hydro-benzoic acid; p-methyl-benzoic acid; m-methyl-benzoic acid; solubility in water; Wilson equation; lambda H equation;

D O I：

10.1016/j.fluid.2006.10.014

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Using a laser monitoring observation technique, solubilities of o-nitro-benzoic acid, p-hydro-benzoic acid, p-methyl-benzoic acid and m-methylbenzoic acid in water have been measured in the temperature range 290.15-323.15 K. The experimental data are regressed with the Wilson equation and the; H equation. The experimental results show that solubilities of these compounds in the range of 10(-4)-10(-5) mole fraction in water, increase significantly with temperature. Except for o-nitro-benzoic acid, the solubility data are described adequately with the Wilson equation. The lambda H equation gives good agreement with all experimental data. The results indicate that the molecular structure and interactions affect the solubilities significantly. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：165 / 172

页数：8

共 23 条

[1]

ANTONIO F, 2001, CHEMOSPHERE, V45, P1063

[2] The solubilities of benzene polycarboxylic acids in water [J].

Apelblat, A ;

Manzurola, E ;

Balal, NA .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2006, 38 (05) :565-571

[3] Solubilities of L-aspartic, DL-aspartic, DL-glutamic, p-hydroxybenzoic, o-anistic, p-anisic, and itaconic acids in water from T = 278 K to T = 345 K [J].

Apelblat, A ;

Manzurola, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1997, 29 (12) :1527-1533

[4] DETERMINING CHEMICAL TOXICITY TO AQUATIC SPECIES [J].

BLUM, DJW ;

SPEECE, RE .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1990, 24 (03) :284-293

[5] SOLUBILITY OF SOLIDS IN LIQUIDS - ONE-PARAMETER SOLUBILITY EQUATION [J].

BUCHOWSKI, H ;

KHIAT, A .

FLUID PHASE EQUILIBRIA, 1986, 25 (03) :273-278

[6] SOLVENT ACTIVITY ALONG A SATURATION LINE AND SOLUBILITY OF HYDROGEN-BONDING SOLIDS [J].

BUCHOWSKI, H ;

KSIAZCZAK, A ;

PIETRZYK, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (09) :975-979

[7] VAPOR LIQUID SOLID EQUILIBRIUM OF EICOSANOIC ACID IN ONE-COMPONENT AND 2-COMPONENT SOLVENTS [J].

DOMANSKA, U .

FLUID PHASE EQUILIBRIA, 1986, 26 (02) :201-220

[8]

HAN SJ, 1991, PHASE EQUILIBRIA CHE

[9]

LANDOLFBORNSFEI, 1995, NEW SERIES GROUP, V8

[10] MOLECULAR DIAGNOSTICS FOR POLYCHLORINATED BIPHENYL DEGRADATION IN CONTAMINATED SOILS [J].

LAYTON, AC ;

LAJOIE, CA ;

EASTER, JP ;

JERNIGAN, R ;

BECK, MJ ;

SAYLER, GS .

RECOMBINANT DNA TECHNOLOGY II, 1994, 721 :407-422

← 1 2 3 →