New Composite Nanomaterials with Antimicrobial and Photocatalytic Properties Based on Silver and Zinc Oxide

被引:16
作者
Dumbrava, Anca [1 ]
Berger, Daniela [2 ]
Matei, Cristian [2 ]
Prodan, Gabriel [3 ]
Aonofriesei, Florin [4 ]
Radu, Marius Daniel [4 ]
Moscalu, Florin [5 ]
机构
[1] Ovidius Univ Constanta, Dept Chem & Chem Engn, Constanta, Romania
[2] Univ Politehn Bucuresti, Dept Inorgan Chem Phys Chem & Electrochem, Bucharest, Romania
[3] Ovidius Univ Constanta, Electron Microscopy Lab, Constanta, Romania
[4] Ovidius Univ Constanta, Fac Nat & Agr Sci, Constanta, Romania
[5] Ovidius Univ Constanta, Dept Phys, Constanta, Romania
关键词
Ag-ZnO nanocomposites; Biosynthetic method; Nanobio silver; Photocatalytic activity; Antimicrobial activity; SYNERGISTIC ANTIBACTERIAL ACTIVITY; OPTICAL-PROPERTIES; GREEN SYNTHESIS; AG NANOPARTICLES; ZNO; DEGRADATION; ANTHOCYANINS; LIGHT; NANOSTRUCTURES; NANOPOWDERS;
D O I
10.1007/s10904-019-01166-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Herein we report the synthesis of composites containing nanobio silver, ZnO and phytochemicals in different Ag/Zn molar ratios. First, Ag nanoparticles were prepared using red cabbage extract and then they are covered with zinc oxide obtained also in the same extract by precipitation method. The antimicrobial activity of synthesized nanocomposites was tested against Staphylococcus aureus, Streptococcus, Escherichia coli, Pseudomonas and Candida clinical isolates and compared with that of ZnO functionalized with anthocyanins. The presence of nanobio silver into the nanocomposites enhanced the bactericidal properties demonstrated by slightly larger diameters of growth inhibition zone and lower minimal inhibitory concentrations. S. aureus and Streptococcus strains were more sensitive than the other strains and fungi both for Ag-ZnO nanocomposites and ZnO functionalized with anthocyanins. Also, the presence of silver in the nanocomposites leads to an improved photocatalytic activity (PA) confirmed in the bleaching of Congo red solution. The PA increases with silver content when Ag content is low (up to 1/12 Ag/Zn molar ratio), but decreases significantly for high silver concentration (1/7 Ag/ZnO molar ratio) in the Ag-ZnO nanocomposites.
引用
收藏
页码:2072 / 2082
页数:11
相关论文
共 54 条
[1]  
Abdel-Raouf N., 2018, Beni-Suef University Journal of Basic and Applied Sciences, V7, P150, DOI DOI 10.1016/J.BJBAS.2017.10.003
[2]   Green synthesis of Ag/ZnO nanohybrid using sodium alginate gelation method [J].
Abou Oualid, Hicham ;
Essamlali, Younes ;
Amadine, Othmane ;
Daanoun, Karim ;
Zahouily, Mohamed .
CERAMICS INTERNATIONAL, 2017, 43 (16) :13786-13790
[3]  
Agarwal Happy, 2017, Resource-Efficient Technologies, V3, P406, DOI 10.1016/j.reffit.2017.03.002
[4]  
Ahmed S, 2017, J PHOTOCH PHOTOBIO B, V166, P272, DOI [10.1016/j.JPhotobiol.2016.12.011, 10.1016/j.jphotobiol.2016.12.011]
[5]  
[Anonymous], 2003, M2A8 NAT COMM CLIN L
[6]  
[Anonymous], 2000, ENCY ANAL CHEM
[7]  
[Anonymous], 1999, M26A NAT COMM CLIN L
[8]   Enhanced Antibacterial Activity of Nanocrystalline ZnO Due to Increased ROS-Mediated Cell Injury [J].
Applerot, Guy ;
Lipovsky, Anat ;
Dror, Rachel ;
Perkas, Nina ;
Nitzan, Yeshayahu ;
Lubart, Rachel ;
Gedanken, Aharon .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (06) :842-852
[9]  
Baker S, 2016, ENZYME MICROB TECHNO, V95, P128, DOI [10.1016/j.enzmictec.2016.10.004, DOI 10.1016/J.ENZMICTEC.2016.10.004]
[10]   Photocatalytic activity of ZnO doped with Ag on the degradation of endocrine disrupting under UV irradiation and the investigation of its antibacterial activity [J].
Bechambi, Olfa ;
Chalbi, Manel ;
Najjar, Wahiba ;
Sayadi, Sami .
APPLIED SURFACE SCIENCE, 2015, 347 :414-420