A novel catalytic one-pot synthesis of carbazoles via consecutive amination and C-H activation

被引:112
作者
Bedford, RB [1 ]
Cazin, CSJ [1 ]
机构
[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
关键词
D O I
10.1039/b207712b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sequential palladium catalysed amination and C-H activation reactions occur between 2-chloro-N-alkylated anilines and aryl bromides to give carbazoles in one pot.
引用
收藏
页码:2310 / 2311
页数:2
相关论文
共 11 条
[1]   PALLADIUM-CATALYZED CYCLIZATION OF 2-SUBSTITUTED HALOGENOARENES BY DEHYDROHALOGENATION [J].
AMES, DE ;
OPALKO, A .
TETRAHEDRON, 1984, 40 (10) :1919-1925
[2]  
AMES DE, 1983, SYNTHESIS-STUTTGART, P234
[3]   Highly active catalysts for the Suzuki coupling of aryl chlorides [J].
Bedford, RB ;
Cazin, CSJ .
CHEMICAL COMMUNICATIONS, 2001, (17) :1540-1541
[4]  
Hagelin H, 1999, CHEM-EUR J, V5, P2413, DOI 10.1002/(SICI)1521-3765(19990802)5:8<2413::AID-CHEM2413>3.0.CO
[5]  
2-3
[6]   Room-temperature palladium-catalyzed amination of aryl bromides and chlorides and extended scope of aromatic C-N bond formation with a commercial ligand [J].
Hartwig, JF ;
Kawatsura, M ;
Hauck, SI ;
Shaughnessy, KH ;
Alcazar-Roman, LM .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (15) :5575-5580
[7]   Novel synthetic strategy of carbolines via palladium-catalyzed amination and arylation reaction [J].
Iwaki, T ;
Yasuhara, A ;
Sakamoto, T .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (11) :1505-1510
[8]  
Martín-Matute B, 2001, CHEM-EUR J, V7, P2341, DOI 10.1002/1521-3765(20010601)7:11<2341::AID-CHEM23410>3.0.CO
[9]  
2-S
[10]   Practical palladium catalysts for C-N and C-O bond formation [J].
Muci, AR ;
Buchwald, SL .
CROSS-COUPLING REACTIONS: A PRACTICAL GUIDE, 2002, 219 :131-209