Effect of Magnesium Addition to PtSnNa/ZSM-5 on the Catalytic Properties in the Dehydrogenation of Propane

被引：42

作者：

Bai, Linyang ^{[1
]}

Zhou, Yuming ^{[1
]}

Zhang, Yiwei ^{[1
]}

Liu, Hui ^{[1
]}

Sheng, Xiaoli ^{[1
]}

机构：

[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2009年 / 48卷 / 22期

关键词：

BIMETALLIC PT-SN/AL2O3 CATALYSTS; N-BUTANE DEHYDROGENATION; SUPPORTED PTSN CATALYSTS; ISOBUTANE DEHYDROGENATION; OXIDATIVE DEHYDROGENATION; SELECTIVE DEHYDROGENATION; SURFACE-STRUCTURE; LIGHT PARAFFINS; METALLIC PHASE; SN CATALYSTS;

D O I：

10.1021/ie900534m

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The effect of Mg addition to PtSnNa/ZSM-5 on the catalytic properties in propane dehydrogenation was investigated. The catalysts were characterized by using different techniques: XRD, BET, TEM, NH3-TPD, XPS, TPO, and TG-DTA. Results indicate that the presence of magnesium not only modifies the acid funcfion and the structure of metallic phase but also diminishes carbon deposition on the catalyst. Among the catalysts studied, the PtSnNaMg(0.5%)/ZSM-5 exhibits the best performance in terms of propane conversion and stability. The high catalytic performance may be due to the strong interaction between Pt and Sri.

引用

页码：9885 / 9891

页数：7

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