Electrochemical lithium storage performance of three-dimensional foam-like biocarbon/MoS2 composites

被引:15
作者
Ma, Bei-bei [1 ]
Chen, Shui-jiao [1 ]
Huang, Ye-wei [1 ]
Nie, Zhen-zhen [1 ]
Qiu, Xiao-bin [1 ]
Xie, Xiu-qiang [2 ]
Wu, Zhen-jun [1 ]
机构
[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Peoples R China
[2] Hunan Univ, Coll Mat Sci & Engn, Changsha 410082, Peoples R China
基金
中国国家自然科学基金;
关键词
electrochemical lithium storage performance; lithium-ion batteries; camellia dregs; MoS2; composites; pseudocapacity; anode;
D O I
10.1016/S1003-6326(21)65492-4
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Molybdenum disulfide (MoS2) was loaded on biocarbon using waste camellia dregs (CDs) as the carbon source, which was further coated with dopamine hydrochloride to construct biocarbon/MoS2 electrode composites. The electrochemical lithium storage performance of the composites with different MoS2 contents was investigated. SEM results demonstrated that the composite had a three-dimensional foam-like structure with MoS2 as the interlayer. XRD and HRTEM tests revealed that MoS2 interlayer spacing in the composite was expanded. XPS analysis showed that new Mo-N bonds were formed in the active material. The electrochemical tests showed that the composite with a MoS2 content of 63% had a high initial specific capacity of 1434 mA.h/g at a current density of 100 mA/g. After a long cycle at a high current, it also showed good cycling stability and the capacity retention was nearly 100%. In addition, it had good lithium ion deintercalation ability in the electrochemical kinetics test.
引用
收藏
页码:255 / 264
页数:10
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