The 3D supramolecular compound {[Cu2(L-val)2(4,4′-bipy)(H2O)2](NO3)2}n (L-val = L-valine anion, 4,4′-bipy=4,4′-bipyridine)

被引:13
作者
Lou, Benyong [1 ]
Huang, Xiaodong [1 ]
Lin, Xiangchao [1 ]
机构
[1] Minjiang Univ, Dept Chem & Chem Engn, Fuzhou 350108, Fujian, Peoples R China
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 03期
关键词
copper; amino acids; hydrogen bonding; COORDINATION POLYMERS; MOLECULES; DESIGN; NETWORKS; CHAINS; HELIX;
D O I
10.1002/zaac.200600295
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
{[Cu-2(L-val)(2)(4,4'-bipy)(H2O)(2)](NO3)(2)}(n) was synthesized and its crystal structure was determined by X-ray diffraction. In the presence of 4,4'-bipyridine, deprotoned L-valine chelates Cu-II ions into coordination layers which were linked into a framework by hydrogen-bonded chains resulting from nitrate anions and water molecules.
引用
收藏
页码:372 / 374
页数:3
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