Magnetic field-induced effects on the melting temperatures of polymer gels

被引:13
作者
Matsumoto, Y
Yamamoto, I
Yamaguchi, M
Shimazu, Y
Ishikawa, F
机构
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS | 1997年 / 36卷 / 10B期
关键词
high magnetic field; polymer; sol-gel phase change; temperature-induced phase change; agarose; methyl cellulose;
D O I
10.1143/JJAP.36.L1397
中图分类号
O59 [应用物理学];
学科分类号
摘要
The gel-melting temperature was observed for aqueous agarose and aqueous methyl cellulose gels which were prepared under the influence of magnetic fields up to 5 T. The exposure to magnetic fields during gelation caused the melting temperature to increase in the agarose gels (+1.0K for the 0.2 wt% gel) and to decrease in methyl cellulose gels (-3.5 K for the 0.4 wt% gel). The change in melting temperature was reduced with increasing polymer concentration and was saturated in magnetic fields below 3 T. Stable gel structures were constructed due to the exposure to magnetic fields.
引用
收藏
页码:L1397 / L1399
页数:3
相关论文
共 9 条
[1]   STRUCTURE OF THE AGAROSE CONSTITUENT OF AGAR-AGAR [J].
ARAKI, C .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1956, 29 (04) :543-544
[2]   STUDIES OF THE AGAROSE GELLING SYSTEM BY THE FLUORESCENCE POLARIZATION METHOD .3. [J].
HAYASHI, A ;
KINOSHITA, K ;
YASUEDA, S .
POLYMER JOURNAL, 1980, 12 (07) :447-453
[3]  
KALKWARF DR, 1979, DOE S SER, V50, P408
[4]   MELTING TEMPERATURES OF THERMALLY REVERSIBLE GELS .4. METHYL CELLULOSE-WATER GELS [J].
KATO, T ;
YOKOYAMA, M ;
TAKAHASHI, A .
COLLOID AND POLYMER SCIENCE, 1978, 256 (01) :15-21
[5]   RECENT BIOPHYSICAL STUDIES IN HIGH MAGNETIC-FIELDS [J].
MARET, G .
PHYSICA B, 1990, 164 (1-2) :205-212
[6]  
MARK HF, 1965, ENCY POLYM SCI TECHN, V3, P131
[7]  
NAGAKURA S, 1992, CHEM PHYS, V162, pU1
[8]   MAGNETIC-FIELD EFFECT ON THE POLYMERIZATION OF FIBRIN FIBERS [J].
YAMAGISHI, A ;
TAKEUCHI, T ;
HIGASHI, T ;
DATE, M .
PHYSICA B, 1990, 164 (1-2) :222-228
[9]   Chemical equilibrium of the ferromagnetic LaCo5-H system in strong magnetic fields [J].
Yamamoto, I ;
Yamaguchi, M ;
Goto, T ;
Miura, S .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 231 (1-2) :205-207