Gas chromatography method for the characterization of ethanol steam reforming products

被引：4

作者：

Chladek, Petr ^{[1
]}

Coleman, Luke J. I. ^{[1
]}

Croiset, E. ^{[1
]}

Hudgins, Robert R. ^{[1
]}

机构：

[1] Univ Waterloo, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada

来源：

JOURNAL OF CHROMATOGRAPHIC SCIENCE | 2007年 / 45卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1093/chromsci/45.3.153

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Ethanol steam reforming is a promising reaction for producing fuel cell hydrogen. Depending on catalyst and reaction conditions, mixtures of condensable hydrocarbons and organic and inorganic gases are produced. This paper proposes an economic and effective solution for separating and detecting these compounds employing a gas chromatograph equipped with two columns, two 6-way valves, and two detectors.

引用

页码：153 / 157

页数：5

共 16 条

[1] Experimental studies and comprehensive reactor modeling of hydrogen production by the catalytic reforming of crude ethanol in a packed bed tubular reactor over a Ni/Al2O3 catalyst [J].

Aboudheir, A ;

Akande, A ;

Idem, R ;

Dalai, A .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2006, 31 (06) :752-761

[2] Synthesis, characterization and performance evaluation of Ni/Al2O3 catalysts for reforming of crude ethanol for hydrogen production [J].

Akande , AJ ;

Idem, RO ;

Dalai, AK .

APPLIED CATALYSIS A-GENERAL, 2005, 287 (02) :159-175

[3] Bio-ethanol catalytic steam reforming over supported metal catalysts [J].

Auprêtre, F ;

Descorme, C ;

Duprez, D .

CATALYSIS COMMUNICATIONS, 2002, 3 (06) :263-267

[4] Characterization of the activity and stability of supported cobalt catalysts for the steam reforming of ethanol [J].

Batista, MS ;

Santos, RKS ;

Assaf, EM ;

Assaf, JM ;

Ticianelli, EA .

JOURNAL OF POWER SOURCES, 2003, 124 (01) :99-103

[5] Hydrogen production by auto-thermal reforming of ethanol on Rh/Al2O3 catalyst [J].

Cavallaro, S ;

Chiodo, V ;

Vita, A ;

Freni, S .

JOURNAL OF POWER SOURCES, 2003, 123 (01) :10-16

[6] Hydrogen production by ethanol reforming over Rh/CeO2-ZrO2 catalysts [J].

Diagne, C ;

Idriss, H ;

Kiennemann, A .

CATALYSIS COMMUNICATIONS, 2002, 3 (12) :565-571

[7] Production of hydrogen for fuel cells by reformation of biomass-derived ethanol [J].

Fatsikostas, AN ;

Kondarides, DI ;

Verykios, XE .

CATALYSIS TODAY, 2002, 75 (1-4) :145-155

[8] Rh based catalysts for indirect internal reforming ethanol applications in molten carbonate fuel cells [J].

Freni, S .

JOURNAL OF POWER SOURCES, 2001, 94 (01) :14-19

[9] Synthesis gas production by steam reforming of ethanol [J].

Galvita, VV ;

Semin, GL ;

Belyaev, VD ;

Semikolenov, VA ;

Tsiakaras, P ;

Sobyanin, VA .

APPLIED CATALYSIS A-GENERAL, 2001, 220 (1-2) :123-127

[10]

GUDZINOWICZ BJ, 1967, PRACTICE CHROMATOGRA, P246

← 1 2 →