Amino-salicylaldimine-palladium(II) complexes: New and efficient catalysts for Suzuki and Heck reactions

被引：41

作者：

Cui, Jin ^{[1
]}

Zhang, Mingjie ^{[1
]}

Zhang, Yuwei ^{[2
]}

机构：

[1] Tianjin Univ, Dept Chem, Sch Sci, Tianjin 300072, Peoples R China

[2] Tianjin Inst Urban Construct, Dept Basic Sci, Tianjin 300384, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 01期

关键词：

Suzuki-Miyaura; Heck-Mizoroki; Amino-salicylaldimine; Palladium; Catalysis; CROSS-COUPLING REACTIONS; N-HETEROCYCLIC CARBENES; HETEROARYL HALIDES; ROOM-TEMPERATURE; MIZOROKI-HECK; DERIVATIVES; ACIDS;

D O I：

10.1016/j.inoche.2009.10.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of amino-salicylaldimine-palladium(II) complexes bearing 5-methyl-3-(R-1-ylmethyl)-salicylaldimine ligands (R = morpholine, piperidine, pyrrolidine, 4-methylpiperazin, diisopropylamine) have been prepared and characterized by IR, H-1 NMR and elemental analysis. Crystal structure details of complex 2b have been confirmed by X-ray structure analysis. The obtained Pd(II) complexes were found to be effective catalysts for the Suzuki and Heck cross-coupling reactions Which Could be carried Out in the undried solvent under air. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：81 / 85

页数：5

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