Distinguishing two contributions to the nearly constant loss in ion-conducting glasses

被引:42
|
作者
Sidebottom, DL [1 ]
Murray-Krezan, CM [1 ]
机构
[1] Univ New Mexico, Dept Chem & Nucl Engn, Albuquerque, NM 87131 USA
关键词
D O I
10.1103/PhysRevLett.89.195901
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In an effort to understand the origins of the nearly constant loss in disordered materials, we report dielectric studies of a series of sodium germanate glasses, (Na2O)(x)(GeO2)(1-x) for x=0, 0.003, 0.01, 0.03, and 0.1 at temperatures between 85 and 700 K. Analysis of the conductivity scaling for these glasses demonstrates the existence of two contributions in the near constant loss; one due to mobile cations that conforms to the same scaling properties found for ion hopping at high temperatures and the other due to the glass network which dominates at low temperatures and low ion densities.
引用
收藏
页数:4
相关论文
共 50 条
  • [1] Nearly constant loss or constant loss in ionically conducting glasses: A physically realizable approach
    Macdonald, JR
    JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (13): : 6192 - 6199
  • [2] NEW LITHIUM ION-CONDUCTING GLASSES
    KADONO, K
    MITANI, K
    YAMASHITA, M
    TANAKA, H
    SOLID STATE IONICS, 1991, 47 (3-4) : 227 - 230
  • [3] Microwave melting of ion-conducting glasses
    Duval, DJ
    Terjak, MJE
    Risbud, SH
    Phillips, BL
    MICROWAVE PROCESSING OF MATERIALS V, 1996, 430 : 125 - 129
  • [4] Free volumes in several ion-conducting glasses
    Doi, A
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 246 (1-2) : 155 - 158
  • [5] Scaling of the ac permittivity in ion-conducting glasses
    Sidebottom, DL
    Zhang, J
    PHYSICAL REVIEW B, 2000, 62 (09) : 5503 - 5507
  • [6] Structure and conductivity of fast ion-conducting borate glasses
    Swenson, J
    Borjesson, L
    McGreevy, RL
    Howells, WS
    PHYSICA B, 1997, 234 : 386 - 387
  • [7] Diffusion in Ion-conducting Oxide Glasses and in Glassy Metals
    Mehrer, Helmut
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2009, 223 (10-11): : 1143 - 1160
  • [8] Tracer diffusion studies of ion-conducting chalcogenide glasses
    Bychkov, E
    SOLID STATE IONICS, 2000, 136 : 1111 - 1118
  • [9] The ionic transition and the glass transition in ion-conducting glasses
    Doi, A
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2006, 352 (05) : 469 - 472
  • [10] Preparation and characterization of lithium ion-conducting oxysulfide glasses
    Minami, T
    Hayashi, A
    Tatsumisago, M
    SOLID STATE IONICS, 2000, 136 : 1015 - 1023