Heterometallic CeIII-FeIII-salicylate networks:: models for corrosion mitigation of steel surfaces by the 'Green' inhibitor, Ce(salicylate)3

被引：49
作者：
Deacon, GB [1 ]
Forsyth, CM
Behrsing, T
Konstas, K
Forsyth, M
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3168, Australia
[2] Monash Univ, Sch Phys & Mat Engn, Clayton, Vic 3168, Australia
[3] Monash Univ, Ctr Green Chem, Clayton, Vic 3168, Australia
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 23期
关键词：
D O I：
10.1039/b207722a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The syntheses and structures of the novel Ce-Fe bimetallic complexes [{Fe(sal)(2)(bpy)}(2)Ce(NO3)(H2O)(3)].EtOH and [{Fe(sal)(2)(bpy)}(4)Ce-2(H2O)(11)][salH](2).EtOH.3H(2)O (salH(2) = salicylic acid) suggest Fe3+-sal(2-) units and Ce-OC(R)O-Fe bridging contribute to the formation of corrosion inhibitive layers on steel surfaces exposed to [Ce(salH)(3)(H2O)].
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页码：2820 / 2821
页数：2
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