Supramolecular Alternating Polymer from Crown Ether and Pillar[5]arene-Based Double Molecular Recognition for Preparation of Hierarchical Materials

被引：26
|
作者：
Li, Hui [1 ,2 ]
Fan, Xiaodong [1 ,2 ]
Qi, Miao [1 ,2 ]
Yang, Zhen [1 ,2 ]
Zhang, Haitao [1 ,2 ]
Tian, Wei [1 ,2 ]
机构：
[1] Northwestern Polytech Univ, Minist Educ, Key Lab Space Appl Phys & Chem, Xian 710072, Peoples R China
[2] Northwestern Polytech Univ, Sch Sci, Shanxi Key Lab Macromol Sci & Technol, Xian 710072, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 01期
关键词：
molecular recognition; hierarchical materials; host-guest interaction; supramolecular polymers; HYPERBRANCHED POLYMER; AMMONIUM-SALT; HOST; WATER; UNITS; COMPLEXATION; CONSTRUCTION; ORGANIZATION; ASSEMBLIES; CHEMISTRY;
D O I：
10.1002/chem.201504012
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel supramolecular alternating polymer is constructed based on double molecular recognition events of benzo-21-crown-7 with a secondary ammonium salt and of pillar[5]arene with a neutral guest. The resulting polymer is utilized to prepare hierarchical materials with different dimensionalities for the first time. These materials included zero-dimensional spherical aggregates, one-dimensional nanofibers, two-dimensional microstructured films, and three-dimensional ordered glue. This development will be helpful for designing and preparing supramolecular hierarchical materials with different dimensionalities.
引用
收藏
页码：101 / 105
页数：5
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