An Efficient Catalytic Sulfonyloxylactonization of Alkenoic Acids Using Hypervalent Iodine(III) Reagent

被引：22

作者：

Yan, Jie ^{[1
]}

Wang, Hong ^{[1
]}

Yang, Zhenping ^{[1
]}

He, Yan ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310032, Zhejiang, Peoples R China

来源：

SYNLETT | 2009年 / 16期

关键词：

sulfonyloxylactonization; hypervalent iodine reagent; catalytic cyclization; M-CHLOROPERBENZOIC ACID; ALPHA-TOSYLOXYKETONES; KETONES; CONVERSION; SALTS; PHI;

D O I：

10.1055/s-0029-1217977

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient catalytic method for sulfonyloxylactonization of alkenoic acids is reported. (Diacetoxyiodo) benzene could be used as a recyclable catalyst in combination with m-chloroperbenzoic acid as an oxidant in the presence of sulfonic acid to effect the cyclization of various alkenoic acids in CH2Cl2 at room temperature, giving sulfonyloxylactones in good yields.

引用

页码：2669 / 2672

页数：4

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