Influence of Magnetic Field on the Electrodeposition and Capacitive Performances of MnO2

被引:5
作者
Girimonte, Aldo [1 ,2 ]
Stefani, Andrea [1 ]
Innocenti, Massimo [3 ]
Fontanesi, Claudio [1 ]
Giovanardi, Roberto [1 ]
机构
[1] Univ Modena & Reggio Emilia, Dept Engn Enzo Ferrari, Via Vivarelli 10, I-41125 Modena, Italy
[2] NOVAC Srl, Via Vivarelli 10, I-41125 Modena, Italy
[3] Univ Florence, Chem Dept Ugo Schiff, Via Lastruccia 3, I-50019 Sesto Fiorentino, Italy
关键词
supercapacitor; manganese dioxide; electrodeposition; magnetohydrodynamics; magnetohydrodynamic (MHD); pseudocapacitor; CHARGE STORAGE MECHANISM; ENERGY-STORAGE; ELECTROCHEMISTRY;
D O I
10.3390/magnetochemistry7020019
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This study focuses on the influence of an applied external magnetic field on the electrodeposition process and capacitive performances of MnO2, as pseudo-capacitive active material for supercapacitors electrodes. MnO2 was electrochemically deposited on Si/Au substrates in the presence and in the absence of a 0.5 T magnet, and its capacitive performance was tested via electrochemical characterization. The samples obtained in the presence of the magnetic field show a positive influence on the deposition process: the increase in deposition efficiency leads to more compact and uniform MnO2 coatings, with a decrease in capacitance values for the samples produced with the magnetic field.
引用
收藏
页码:1 / 18
页数:18
相关论文
共 21 条
[1]   Heteroatom doped high porosity carbon nanomaterials as electrodes for energy storage in electrochemical capacitors: A review [J].
Abbas, Qaisar ;
Raza, Rizwan ;
Shabbir, Imran ;
Olabi, A. G. .
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES, 2019, 4 (03) :341-352
[2]   Minimizing the Nyquist-plot semi-circle of pseudocapacitive manganese oxides through modification of the oxide-substrate interface resistance [J].
Allison, A. ;
Andreas, H. A. .
JOURNAL OF POWER SOURCES, 2019, 426 :93-96
[3]  
Bard AJ., 1980, Electrochemical Methods: Fundamentals and Applications
[4]  
Conway B.E., 2013, Electrochemical supercapacitors: scientific fundamentals and technological applications
[5]   The role and utilization of pseudocapacitance for energy storage by supercapacitors [J].
Conway, BE ;
Birss, V ;
Wojtowicz, J .
JOURNAL OF POWER SOURCES, 1997, 66 (1-2) :1-14
[6]   Carbon materials for the electrochemical storage of energy in capacitors [J].
Frackowiak, E ;
Béguin, F .
CARBON, 2001, 39 (06) :937-950
[7]   Poly(cyano-substituted diheteroareneethylene) as active electrode material for electrochemical supercapacitors [J].
Fusalba, F ;
Ho, HA ;
Breau, L ;
Bélanger, D .
CHEMISTRY OF MATERIALS, 2000, 12 (09) :2581-2589
[8]   Use of magnetic fields in electrochemistry: A selected review [J].
Gatard, Vivien ;
Deseure, Jonathan ;
Chatenet, Marian .
CURRENT OPINION IN ELECTROCHEMISTRY, 2020, 23 :96-105
[9]  
Gregory R.D., 2006, CLASSICAL MECH, DOI DOI 10.1017/CBO9780511803789
[10]   Magnetic field effects on copper electrolysis [J].
Hinds, G ;
Spada, FE ;
Coey, JMD ;
Mhíocháin, TRN ;
Lyons, MEG .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (39) :9487-9502