共 31 条
Bringing High-Rate, CO2-Based Microbial Electrosynthesis Closer to Practical Implementation through Improved Electrode Design and Operating Conditions
被引:141
作者:
Jourdin, Ludovic
[1
,2
,3
]
Freguia, Stefano
[1
,2
]
Flexer, Victoria
[1
,4
]
Keller, Jurg
[1
]
机构:
[1] Univ Queensland, Adv Water Management Ctr, Gehrmann Bldg, Brisbane, Qld 4072, Australia
[2] Univ Queensland, Ctr Microbial Electrochem Syst, Gehrmann Bldg, Brisbane, Qld 4072, Australia
[3] Wageningen Univ, Sub Dept Environm Technol, NL-6700 AP Wageningen, Netherlands
[4] Ctr Invest & Transferencia Jujuy Conicet, Av Bolivia 1239, RA-4600 San Salvador De Jujuy, Argentina
基金:
澳大利亚研究理事会;
关键词:
COMMODITY CHEMICALS;
CARBON-DIOXIDE;
ACETATE;
ACID;
D O I:
10.1021/acs.est.5b04431
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
The enhancement of microbial electrosynthesis (MES) of acetate from CO2 to performance levels that could potentially support practical implementations of the technology must go through the optimization of key design and operating conditions. We report that higher proton availability drastically increases the acetate production rate, with pH 5.2 found to be optimal, which will likely suppress methanogenic activity without inhibitor addition. Applied cathode potential as low as 1.1 V versus SHE still achieved 99% of electron recovery in the form of acetate at a current density of around 200 A m(-2). These current densities are leading to an exceptional acetate production rate of up to 1330 g m(2) clay at pH 6.7. Using highly open macroporous reticulated vitreous carbon electrodes with macropore sizes of about 0.6 mm in diameter was found to be optimal for achieving a good balance between total surface area available for biofilm formation and effective mass transfer between the bulk liquid and the electrode and biofilm surface. Furthermore, we also successfully demonstrated the use of a synthetic biogas mixture as carbon dioxide source, yielding similarly high MES performance as pure CO2. This would allow this process to be used effectively for both biogas quality improvement and conversion of the available CO2 to acetate.
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页码:1982 / 1989
页数:8
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