Electrophilic reactivity of the (phenyl)Cr(CO)3-substituted α-propargyl cation

被引：18
|
作者：
Netz, A [1 ]
Müller, TJJ [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
TETRAHEDRON | 2000年 / 56卷 / 25期
关键词：
D O I：
10.1016/S0040-4020(00)00339-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactivity of the (phenyl)Cr(CO)(3)-substituted alpha-propargyl cation 2 was quantified by measuring the kinetics of nucleophilic trapping reactions. In comparison to related dicobalthexacarbonyl alkynyl substituted carbenium ions the electiophilicity E of 2 is by 2.5 orders of magnitude larger and, thus, this species is more reactive. (C) 2000 Elsevier Science Ltd. All rights reserved.
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收藏
页码：4149 / 4155
页数：7
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