Removal of iron and manganese from aqueous solutions using carbon nanotube filters

被引:18
作者
Elsehly, E. M. I. [1 ,2 ]
Chechenin, N. G. [1 ]
Bukunov, K. A. [1 ]
Makunin, A. V. [1 ]
Priselkova, A. B. [1 ]
Vorobyeva, E. A. [1 ]
Motaweh, H. A. [2 ]
机构
[1] Moscow MV Lomonosov State Univ, Skobeltsyn Inst Nucl Phys, Moscow, Russia
[2] Damanhour Univ, Fac Sci, Damanhour, Egypt
来源
WATER SCIENCE AND TECHNOLOGY-WATER SUPPLY | 2016年 / 16卷 / 02期
关键词
iron; manganese; MWCNT; WATER; FUNCTIONALIZATION; DESALINATION;
D O I
10.2166/ws.2015.143
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Carbon nanotubes (CNTs) have become the focus of attention of many scientists and companies worldwide. CNT-based filters have a prospective advantage in comparison to the commercial filters already in operation because they are light weight and do not require electricity to operate. This investigation handles the filtration efficiency of manganese and iron from aqueous solution using commercial multiwalled carbon nanotubes (MWCNTs) (Taunit). The effects of different parameters such as CNT filter mass, concentration of manganese and iron in aqueous solution and pH of aqueous solution on removal of these heavy metals are determined. From these investigations, the removal efficiency of manganese and iron could reach 71.5% and 52% respectively for concentration 50 ppm, suggesting that Taunit is an excellent adsorbent for manganese and iron removal from water. There was a significant increase in removal efficiency at pH = 3 for manganese and pH = 8 for iron. The effect of oxidation on the structural of MWCNTs was characterized by scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS) techniques to investigate the functionalization with oxygen-containing and outer diameter distribution. It was found that functionalized CNT-based filters are more efficient at removing manganese and iron from aqueous solutions. Oxidized MWCNTs may be a promising candidate for heavy metal ion removal from industrial wastewater.
引用
收藏
页码:347 / 353
页数:7
相关论文
共 19 条
[1]   Influence of surface functionalization via chemical oxidation on the properties of carbon nanotubes [J].
Chen, Jiuling ;
Chen, Qinghai ;
Ma, Qing .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2012, 370 :32-38
[2]   Iron and manganese removal and membrane fouling during UF in conjunction with prechlorination for drinking water treatment [J].
Choo, KH ;
Lee, H ;
Choi, SJ .
JOURNAL OF MEMBRANE SCIENCE, 2005, 267 (1-2) :18-26
[3]   Designing carbon nanotube membranes for efficient water desalination [J].
Corry, Ben .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (05) :1427-1434
[4]   Simultaneous adsorption of Ni(II) and Mn(II) ions from aqueous solution unto a Nigerian kaolinite clay [J].
Dawodu, Folasegun Anthony ;
Akpomie, Kovo Godfrey .
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2014, 3 (02) :129-141
[5]  
Dyachkova TP, 2013, NANOSYST-PHYS CHEM M, V4, P605
[6]  
FORSTNER U., 1983, METAL POLLUTION AQUA, V2
[7]   Oxidized multiwalled carbon nanotubes as adsorbent for the removal of manganese from aqueous solution [J].
Ganesan, Pandian ;
Kamaraj, Ramakrishnan ;
Sozhan, Ganapathy ;
Vasudevan, Subramanyan .
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2013, 20 (02) :987-996
[8]   Carbon nanotubes as superior sorbent for dioxin removal [J].
Long, RQ ;
Yang, RT .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (09) :2058-2059
[9]   Removal of nickel(II) from aqueous solution by carbon nanotubes [J].
Lu, Chungsying ;
Liu, Chunti .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2006, 81 (12) :1932-1940
[10]   Efficient technologies for worldwide clean water supply [J].
Macedonio, F. ;
Drioli, E. ;
Gusev, A. A. ;
Bardow, A. ;
Semiat, R. ;
Kurihara, M. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2012, 51 :2-17