(Liquid plus Solid) Equilibrium, Density, and Refractive Index for (Methanol plus Sodium Chloride plus Rubidium Chloride plus Water) and (Ethanol plus Sodium Chloride plus Rubidium Chloride plus Water) at Temperatures of (288, 298, and 308) K

被引：3
作者：
Li, Shuni
Guo, Haiyan
Zhai, Quanguo
Jiang, Yucheng
Hu, Mancheng [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Xian 710062, Shaanxi, Peoples R China
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2009年 / 54卷 / 11期
基金：
中国国家自然科学基金;
关键词：
POTASSIUM-CHLORIDE; CESIUM-CHLORIDE; TERNARY-SYSTEM; QUATERNARY SYSTEMS; DEGREES-C; 25-DEGREES-C; GLYCOL); NITRATE; WATER+1-PROPANOL; SOLUBILITIES;
D O I：
10.1021/je900636w
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
In this paper, (liquid + solid) equilibria, densities, and refractive indices are reported for (CH3OH + NaCl + RbCl + H2O) and (C2H5OH + NaCl + RbCl + H2O) at T = (288.15, 298.15, and 308.15) K. The results show that the presence of either CH3OH or C2H5OH significantly reduces the solubility of NaCl and RbCl in aqueous solutions. The experimental solubility, density, and refractive index were correlated to empirical equations, which makes it possible to calculate these properties over the whole studied concentration. Calculated values are in good agreement with the experimental results.
引用
收藏
页码：3108 / 3111
页数：4
相关论文
共 26 条
  • [21] Liquid-liquid and solid-liquid equilibria of the poly(ethylene glycol) plus sodium sulfate plus water system at 298.15 K
    Taboada, ME
    Rocha, OA
    Graber, TA
    Andrews, BA
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (02) : 308 - 311
  • [22] Solubilities of sodium chloride in organic and aqueous-organic solvent mixtures
    Wagner, K
    Friese, T
    Schulz, S
    Ulbig, P
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1998, 43 (05) : 871 - 875
  • [23] Equilibrium phase behavior for water+1-propanol + potassium chloride plus cesium chloride quaternary systems at different temperatures and data correlation
    Wang, Meixia
    Hu, Mancheng
    Zhai, Quanguo
    Li, Shu'ni
    Jiang, Yucheng
    Guo, Haiyan
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2008, 53 (06) : 1387 - 1392
  • [24] XIA SP, 1987, SALT LAKE RES, V1, P14
  • [25] Thermodynamics of magnesium sulfate-polypropylene glycol aqueous two-phase system. Experiment and correlation
    Zafarani-Moattar, MT
    Salabat, A
    [J]. FLUID PHASE EQUILIBRIA, 1998, 152 (01) : 57 - 65
  • [26] Solubilities, densities and refractive indices of rubidium chloride or cesium chloride in ethanol aqueous solutions at different temperatures
    Zhao Wen-Xia
    Hu Man-Cheng
    Jiang Yu-Cheng
    Li Shu-Ni
    [J]. CHINESE JOURNAL OF CHEMISTRY, 2007, 25 (04) : 478 - 483
123