Temperature-composition dependence of the bandgap and possible non-complanar structures in GaN-AlN, GaN-InN and InN-AlN mixed crystals

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作者
Kalashnikov, EV [1 ]
Nikolaev, VI [1 ]
机构
[1] AF IOFFE PHYS TECH INST, ST PETERSBURG, RUSSIA
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T [工业技术];
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摘要
The virtual crystal approximation has been used to determine the temperature-composition dependence of the GaN-AlN, GaN-InN, and InN-AlN band gap energies. Also, the thermodynamic instability states in:he mixed crystals were studied, The expression for the band gap of mixed A-B crystals has been derived: E-g(AB)=(1-x)E-g(A)+xE(g)(B)-bS(xx), where E-g(A) and E-g(B) are the direct gaps for compounds A and B, respectively, and x is the alloy concentration. The term S(xx)similar to T-0/partial derivative(2)G/partial derivative x(2)) where G is the thermodynamic potential of the mixed crystal, b is a bowing parameter, and T-0 has the meaning of a growth temperature.
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    MRS Internet Journal of Nitride Semiconductor Research, 1997, 2
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