Synthesis and characterization of new cyclic and cage-like indium-phosphorus and indium-arsenic compounds

被引：0
作者：
Hänisch, C [1 ]
Rolli, B [1 ]
机构：
[1] Forschungszentrum Karlsruhe GmbH, Inst Nanotechnol, D-76021 Karlsruhe, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 11期
关键词：
arsenic; indium; phosphorus; crystal structure; cluster compounds;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of InEt3 with H(2)ESiiPr(3) initially yields the cyclic compound [Et2InP(H)SiiPr(3)](2) (2). 2 appears as a mixture of cis and trans isomers and has been characterized by P-31-NMR spectroscopy, IR spectroscopy, and mass spectrometry. 2 decomposes in solution under elimination of ethane during a few days to form (EtInPSiiPr(3)](4) (3) with a cage-like structure. The analogous arsenic compound [EtInAsSiiPr(3)](4) (4) can be prepared by reaction of InEt3 with H(2)AsSiiPr(3). Central structural motif of 3 and 4 is an In4E4 heterocubane like structure (E = P, As), whereas the reaction of InEt3 with H(2)PSiMe(2)Thex (Thex CMe(2)iPr) yields [EtInPSiMe(2)Thex](6) (5) with a hexagonal prismatic structure.
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收藏
页码：2255 / 2258
页数：4
相关论文
共 25 条
  • [1] [Anonymous], SIMULATION AUTOMATIS
  • [2] [(CP(CO)(3)MO)(4)IN-4(PSIME(3))(4)], AN ORGANOMETALLIC IN4P4-HETEROCUBANE
    APP, U
    MERZWEILER, K
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (10): : 1731 - 1734
  • [3] ISOSTERE METALLORGANISCHE VERBINDUNGEN .9. ORGANOGALLOGERMOXANE
    ARMER, B
    SCHMIDBA.H
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1967, 100 (05): : 1521 - &
  • [4] AN INDIUM-PHOSPHORUS HETEROCUBANE AS A NEW-TYPE OF INDIUM-PHOSPHIDE PRECURSOR
    ATWOOD, DA
    COWLEY, AH
    JONES, RA
    MARDONES, MA
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 449 (1-2) : C1 - C2
  • [5] AN ALUMINAPHOSPHACUBANE, A NEW ALUMINUM PHOSPHIDE PRECURSOR
    COWLEY, AH
    JONES, RA
    MARDONES, MA
    ATWOOD, JL
    BOTT, SG
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12): : 1409 - 1410
  • [6] COWLEY AH, 1990, ANGEW CHEM, V102, P1504
  • [7] PREPARATION OF A 4-MEMBERED INDIUM-PHOSPHORUS RING WITH A HYDROGEN-ATOM BOUND TO PHOSPHORUS - CRYSTAL-STRUCTURE OF [(ME3SICH2)2-INPH-TERT-BU]2
    DEMBOWSKI, U
    NOLTEMEYER, M
    ROCKENSUSS, W
    STUKE, M
    ROESKY, HW
    [J]. CHEMISCHE BERICHTE, 1990, 123 (12) : 2335 - 2336
  • [8] Driess M, 1998, CHEM-EUR J, V4, P1628, DOI 10.1002/(SICI)1521-3765(19980904)4:9<1628::AID-CHEM1628>3.0.CO
  • [9] 2-X
  • [10] Driess M, 2000, CHEM-EUR J, V6, P4343, DOI 10.1002/1521-3765(20001201)6:23<4343::AID-CHEM4343>3.0.CO
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