Asymmetric epoxidation of electron-deficient olefins

被引：319
作者：
Porter, MJ
Skidmore, J
机构：
[1] UCL, Christopher Ingold Labs, Dept Chem, London WC1H 0AJ, England
[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 14期
关键词：
D O I：
10.1039/b001780i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In recent years, methods for the asymmetric epoxidation of electron-deficient olefins, particularly alpha,beta-enones, have attracted widespread attention. A critical review is presented of these methods, which include epoxidations with chiral metal hydroperoxides, asymmetric phase-transfer methods, the use of polyamino acid catalysts and the use of chiral dioxiranes.
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页码：1215 / 1225
页数：11
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