Microporous Coordination Polymers As Selective Sorbents for Liquid Chromatography

被引：172

作者：

Ahmad, Rashid ^{[1
,2
,3
]}

Wong-Foy, Antek G. ^{[1
,2
]}

Matzger, Adam J. ^{[1
,2
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Macromol Sci & Engn Program, Ann Arbor, MI 48109 USA

[3] PINSTECH, Div Chem, Directorate Sci, Islamabad, Pakistan

来源：

LANGMUIR | 2009年 / 25卷 / 20期

关键词：

SURFACE-AREA; ADSORPTION; AROMATICS; REMOVAL;

D O I：

10.1021/la902276a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We evaluate the potential of microporous coordination polymers (MCPs) to act as the stationary phase in liquid chromatographic separations. MCPs derived from carboxylates coordinated to copper (HKUST-1) and zinc (MOF-5) were studied. The shape and size selective separation of organic compounds including benzene, ethylbenzene, styrene, naphthalene, anthracene, phenanthrene, pyrene, 1,3,5-triphenylbenzene, and 1,3,5-tris(4-bromophenyl)benzene was performed, and in most cases excellent separation was achieved based on a combination of molecular sieving and adsorption effects.

引用

页码：11977 / 11979

页数：3

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