Copper-catalyzed C-N bond formation using dialkyl azodicarboxylate as the amination reagent

被引：9

作者：

Samzadeh-Kermani, Alireza ^{[1
]}

机构：

[1] Univ Zabol, Dept Chem, Fac Sci, Zabol, Iran

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 04期

关键词：

Aryl hydrazide; C-N cross-coupling; Copper salts; Dialkyl azodicarboxylate; ARYL; ALKYLATION;

D O I：

10.1016/j.tetlet.2015.12.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient copper-catalyzed reaction for C-N bond formation using aryl halides, dialkyl azodicarboxylate, and a hydride source is reported. Using this procedure, aryl iodides reacted at ambient conditions, while aryl bromides required heating to 60 degrees C to accomplish the transformation. Various functional groups were tolerated under the optimum conditions. (C) 2015 Elsevier Ltd. All rights reserved.

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页码：463 / 465

页数：3

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