Syntheses and Crystal Structures of Two New Hg(II) and Cd(II) Complexes with 2,3,5,6-Tetrakis-(2-pyridyl) Pyrazine

被引：0

作者：

Lotfali, Saghatforoush ^{[1
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran, Iran

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 34卷 / 12期

关键词：

Hg(II) complex; Cd(II) complex; tppz; crystal structure; H-1; NMR; 2,3,5,6-TETRA(2-PYRIDYL)PYRAZINE TPPZ; RUTHENIUM(II) COMPLEXES; DINUCLEAR; LIGAND; COPPER(II); TETRA-2-PYRIDYLPYRAZINE;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under thermal gradient in solution phase, the reaction of Hg(II) and Cd(II) salts with 2,3,5,6-tetrakis-(2-pyridyl)pyrazine (tppz) in 1:1 molar ratio afforded dinuclear [{Hgl(2)}2(titppz)] (1) and mononuclear [CdI2(tppz)] (2) complexes. Single -crystal X-ray diffraction structural analysis reveals that the tppz acts as bis-tridentate and tridentate chelating ligands in 1 and 2, respectively. Metal(II) ions adopt a distorted square pyramidal geometry and have the same coordination environment in both complexes. Based on the H-1 NMR spectroscopy measurements, both complexes decompose in solution and release free tppz.

引用

页码：1869 / 1875

页数：7

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