Syntheses and Crystal Structures of Two New Hg(II) and Cd(II) Complexes with 2,3,5,6-Tetrakis-(2-pyridyl) Pyrazine

被引：0
|
作者：
Lotfali, Saghatforoush [1 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 34卷 / 12期
关键词：
Hg(II) complex; Cd(II) complex; tppz; crystal structure; H-1; NMR; 2,3,5,6-TETRA(2-PYRIDYL)PYRAZINE TPPZ; RUTHENIUM(II) COMPLEXES; DINUCLEAR; LIGAND; COPPER(II); TETRA-2-PYRIDYLPYRAZINE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Under thermal gradient in solution phase, the reaction of Hg(II) and Cd(II) salts with 2,3,5,6-tetrakis-(2-pyridyl)pyrazine (tppz) in 1:1 molar ratio afforded dinuclear [{Hgl(2)}2(titppz)] (1) and mononuclear [CdI2(tppz)] (2) complexes. Single -crystal X-ray diffraction structural analysis reveals that the tppz acts as bis-tridentate and tridentate chelating ligands in 1 and 2, respectively. Metal(II) ions adopt a distorted square pyramidal geometry and have the same coordination environment in both complexes. Based on the H-1 NMR spectroscopy measurements, both complexes decompose in solution and release free tppz.
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页码：1869 / 1875
页数：7
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