Heat Transfer under Buoyancy-Induced Flow at the Chemical Reaction Front Using Thermochromic Liquid Crystal Sheet

被引:5
作者
Tanoue, Ken-ichiro [1 ]
Yoshitomi, Masaaki [1 ]
Nishimura, Tatsuo [1 ]
机构
[1] Yamaguchi Univ, Grad Sch Sci & Engn, Dept Mech Engn, Ube, Yamaguchi 7558611, Japan
关键词
Heat Transfer; Natural Convection; Reaction Front; Atwood Number; Dissolution Rate; DRIVEN;
D O I
10.1252/jcej.08we283
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Heat transfer and hydrodynamics at the chemical reaction front have been investigated experimentally using a thermochromic liquid crystal sheet. If the chemical reaction occurs, a band region where the temperature, due to the heat of reaction, is higher than the initial temperature appears at the reaction front. Natural convection due to the temperature difference at the reaction front plays an important role in conveying the higher temperature fluid. For the hydrochloric acid (HCl)-sodium hydroxide (NaOH) system, as the frequency of contact between HCl and NaOH due to convection increases with the concentration of ethanol, the temperature beyond the stagnation point becomes higher than that in other areas. On the other hand, for the acetic acid (CH(3)COOH)-NaOH system, the heat transfer depends mainly on the heat of reaction, because the rate of CH(3)COOH dissolution is smaller than that of HCl.
引用
收藏
页码:255 / 258
页数:4
相关论文
共 7 条
[1]   Chemical pattern formation driven by a neutralization reaction. I. Mechanism and basic features [J].
Eckert, K ;
Acker, M ;
Shi, Y .
PHYSICS OF FLUIDS, 2004, 16 (02) :385-399
[2]   Plume and finger regimes driven by an exothermic interfacial reaction [J].
Eckert, K ;
Grahn, A .
PHYSICAL REVIEW LETTERS, 1999, 82 (22) :4436-4439
[3]  
EIGEN M, 1955, Z ELEKTROCHEM, V59, P986
[4]   Viscous fingering with chemical reaction:: effect of in-situ production of surfactants [J].
Fernandez, J ;
Homsy, GM .
JOURNAL OF FLUID MECHANICS, 2003, 480 :267-281
[5]  
NISHIMURA T, 2006, PHASE T JAPAN SOC ME, V72, P1773
[6]   AN OVERVIEW OF RAYLEIGH-TAYLOR INSTABILITY [J].
SHARP, DH .
PHYSICA D, 1984, 12 (1-3) :3-18
[7]  
Shinohara K, 2005, EXP FLUIDS, V38, P117, DOI [10.1007/s00348-004-0906-z, 10.1007/s00348-004-0906-Z]