Gold and Organocatalysis Combined

被引：147

作者：

Hashmi, A. Stephen K. ^{[1
]}

Hubbert, Christoph ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 06期

关键词：

chiral acids; enantioselective catalysis; gold; sequential reactions; RELAY CATALYSIS; BRONSTED ACID; METAL CATALYSIS; HYDROGENATION; CYCLIZATION; ALDEHYDES; CHEMISTRY;

D O I：

10.1002/anie.200906609

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure presented) All that glitters: Binary catalytic systems of gold(l) complexes and chiral Brønsted acids, which were recently reported by the research groups of Dixon and Gong, represent a significant leap forwards in the area of sequential one-pot reactions. The special feature of these reactions is the isolobal analogy of the proton and [LAu1] cations, which requires a delicate balance between the reactivities of the acids and the gold complexes. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA,.

引用

页码：1010 / 1012

页数：3

共 48 条

[1]

[Anonymous], CATALYTIC ASYMMETRIC

[2]

[Anonymous], ANGEW CHEM

[3] Tandem Enzyme/Gold-Catalysis: From Racemic α-Allenic Acetates to Enantiomerically Enriched 2,5-Dihydrofurans in One Pot [J].

Asikainen, Martta ;

Krause, Norbert .

ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (14-15) :2305-2309

[4]

Belot S., 2009, Angew. Chem., V121, P9085

[5] Enantioselective One-Pot Organocatalytic Michael Addition/Gold-Catalyzed Tandem Acetalization/Cyclization [J].

Belot, Sebastien ;

Vogt, Kim A. ;

Besnard, Celine ;

Krause, Norbert ;

Alexakis, Alexandre .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8923-8926

[6] Direct carbocyclization of aldehydes with alkynes: Combining gold catalysis with aminocatalysis [J].

Binder, Jorg T. ;

Crone, Benedikt ;

Haug, Timm T. ;

Menz, Helge ;

Kirsch, Stefan F. .

ORGANIC LETTERS, 2008, 10 (05) :1025-1028

[7] Tandem Metal and Organocatalysis in Sequential Hydroformylation and Enantioselective Mannich Reactions [J].

Chercheja, Serghei ;

Rothenbuecher, Thomas ;

Eilbracht, Peter .

ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (03) :339-344

[8]

Garcia-Garcia P., 2009, Angew. Chem, V121, P4427, DOI DOI 10.1038/NMETH.3579

[9] A Powerful Chiral Counteranion Motif for Asymmetric Catalysis [J].

Garcia-Garcia, Pilar ;

Lay, Frank ;

Garcia-Garcia, Patricia ;

Rabalakos, Constantinos ;

List, Benjamin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (24) :4363-4366

[10] Room temperature Au(I)-catalyzed exo-selective cycloisomerization of acetylenic acids:: An entry to functionalized γ-lactones [J].

Genin, E ;

Toullec, PY ;

Antoniotti, S ;

Brancour, C ;

Genêt, JP ;

Michelet, V .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (10) :3112-3113

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