Synthesis, Characterization and X-ray Crystal Structure of the Di-Mannich Base 2,2'-(3aR,7aR/3aS,7aS)-Hexahydro-1H-benzo[d]imidazole-1,3(2H)-diyl)bis(methylene)bis(4-methylphenol)

被引：10
|
作者：
Rivera, Augusto [1 ]
Quiroga, Diego [1 ]
Rios-Motta, Jaime [1 ]
Carda, Juan [2 ]
Peris, Gabriel [3 ]
机构：
[1] Univ Nacl Colombia, Dept Quim, Bogota, Colombia
[2] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12071, Spain
[3] Univ Jaume 1, Serv Cent Instrumentacio Cient, Castellon de La Plana 12071, Spain
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2009年 / 39卷 / 11期
关键词：
Di-Mannich bases; 2,2 '-(3aR,7aR/3aS,7aS)-Hexahydro-1H-benzo[d]imidazole-; 1,3(2H)-diyl)bis(methylene)bis(4-methylphenol); Crystal structure; Intramolecular hydrogen bond; Aminal cage; HYDROGEN-BONDS; DERIVATIVES; H-1-NMR; AMINALS; PRODUCT; COMPLEX; SCHIFF; SYSTEM; LIGAND; SALAN;
D O I：
10.1007/s10870-009-9578-0
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of new racemic di-Mannich base 2,2'-(3aR,7aR/3aS,7aS)-hexahydro-1H-benzo[d]imidazole-1,3(2H)-diyl)bis(methylene)bis(4-methylphenol) (4), is reported. The structure of the title compound, C(23)H(30)N(2)O(2), shows two intramolecular O-H center dot center dot center dot N hydrogen bonding interactions. This compound crystallizes in triclinic symmetry, in space group P-1, with lattice constants: a = 6.2563(3) angstrom, b = 12.1743(7) angstrom, c = 14.7257(7) angstrom, alpha = 108.11(1)degrees, beta = 99.77(1)degrees, gamma = 98.78(1), V = 1024.97(9) (3), Z = 2, F(000) = 396, R (1) = 8.3%, wR (2) = 14.7%.
引用
收藏
页码：827 / 830
页数：4
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