Design of Fe-based nanocrystalline alloys with superior magnetization and manufacturability

被引:152
作者
Li, Hu [1 ,2 ]
Wang, Anding [1 ,3 ,4 ]
Liu, Tao [3 ]
Chen, Pingbo [1 ]
He, Aina [1 ]
Li, Qiang [2 ]
Luan, Junhua [3 ]
Liu, Chain-Tsuan [3 ,4 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Magnet Mat & Devices, Ningbo, Zhejiang, Peoples R China
[2] Xinjiang Univ, Sch Phys Sci & Technol, Urumqi, Xinjiang, Peoples R China
[3] City Univ Hong Kong, Coll Sci & Engn, Dept Mat Sci Engn, Kowloon, Hong Kong, Peoples R China
[4] City Univ Hong Kong, Hong Kong Inst Adv Study, Kowloon, Hong Kong, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/j.mattod.2020.09.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fe-based alloys with a nanocrystalline-amorphous nanostructure exhibit superior soft-magnetic performances; however they generally suffer from the low magnetization because of their heavy doping for an acceptable manufacturability. In this study, we proposed a revolutionary nanostructure-construction concept based on preforming dense nuclei in the melt-quenching process with a critical cooling-rate and refining the nano-structure via transient metalloid-rich interfaces. A novel alloy composition of Fe85.5B10Si2P2C0.5 was developed via our multi-metalloid stabilization and critical formability strategies by using a total of only 4.6 wt. % light metalloids. This unique alloy design effort leads to unprecedented magnetic properties with the super-high B-s of 1.87 T and mu(e) of 1.0-2.5 x 10(4), which outperform all commercial counterparts and have a high potential to substitute for commercial bulk Si-steels currently used for soft-magnetic applications. This hetero-structuring and lean-alloying strategy provides a paradigm for the next-generation of magnetic materials.Y
引用
收藏
页码:49 / 56
页数:8
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