Thermally Activated Delayed Fluorescence from Sn4+-Porphyrin Complexes and Their Application to Organic Light-Emitting Diodes - A Novel Mechanism for Electroluminescence

被引：860
作者：
Endo, Ayataka [1 ]
Ogasawara, Mai [2 ]
Takahashi, Atsushi [3 ]
Yokoyama, Daisuke [1 ]
Kato, Yoshimine [2 ]
Adachi, Chihaya [1 ]
机构：
[1] Kyushu Univ, Ctr Future Chem, Nishi Ku, Fukuoka 8190395, Japan
[2] Kyushu Univ, Dept Mat Sci & Engn, Nishi Ku, Fukuoka 8190395, Japan
[3] Sogo Pharmaceut Co Ltd, Iwaki, Fukushima 9728312, Japan
来源：
ADVANCED MATERIALS | 2009年 / 21卷 / 47期
关键词：
DEVICES; ELECTROPHOSPHORESCENCE; PHOSPHORESCENCE;
D O I：
10.1002/adma.200900983
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electroluminescence based on TADF, that is, thermally activated delayed fluorescence, is demonstrated in Sn4+-porphyrin complexes. On excitation by a short electrical pulse, prompt and delayed electroluminescence components were clearly observed. The delayed component was composed of both TADF and phosphorescence (see figure), and the TADF component significantly increased with increasing temperature.
引用
收藏
页码：4802 / +
页数：6
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