Synthesis of metallacarborane ruthenium(II) and ruthenium(III) complexes with chelate 1,3-bis(diphenylphosphino)propane ligand and their mutual transformation in one-electron redox reactions

被引：9

作者：

Grishin, I. D. ^{[1
]}

Agafonova, K. S. ^{[1
]}

Kostyukovich, A. Yu. ^{[2
]}

D'yachihin, D. I. ^{[2
]}

Godovikov, I. A. ^{[2
]}

Dolgushin, F. M. ^{[2
]}

Grishin, D. F. ^{[1
]}

Chizhevsky, I. T. ^{[2
]}

机构：

[1] NI Lobachevsky State Univ Nizhny Novgorod, 23 Prosp Gagarina, Nizhnii Novgorod 603950, Russia

[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Ul Vavilova, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 06期

基金：

俄罗斯基础研究基金会;

关键词：

tris-phosphorus-containing closo-ruthenacarborane; method of synthesis; 1,3-bis(diphenylphosphino)propane; one-electron redox reactions; X-ray diffraction analysis; NMR spectroscopy; ESR; MALDI mass spectrometry; cyclic voltammetry; TRANSFER RADICAL POLYMERIZATION; CLOSO-RUTHENACARBORANES; CARBORANE COMPLEXES; ALIPHATIC-AMINES; CHLORINE DIOXIDE; OXIDATIONS; PHOSPHINOMETALLOCARBORANE; MECHANISM; DUALITY; SYSTEMS;

D O I：

10.1007/s11172-016-1484-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of 12-vertex metallapolyhedra, namely, tris-phosphorus-containing closo-metallacarborane ruthenium(II) cluster </InlineMediaObject>, was synthesized and structurally studied. A principal possibility of the use of aliphatic amines as one-electron reducing agents converting carborane ruthenium(III) complexes to structurally close ruthenium(II) compounds was experimentally demonstrated.

引用

页码：1574 / 1579

页数：6

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