Effect of MgO and BaO on Fe3+/Fe2+ equilibrium in a candidate glass for immobilization of high level nuclear waste

被引:0
作者
Ohashi, S
Okumura, T
Kawamura, K
Miyamoto, Y
Iwase, M
机构
[1] KYOTO UNIV,DEPT ENERGY SCI & TECHNOL,FERROUS MET RES GRP,KYOTO 60601,JAPAN
[2] POWER REACTOR & NUCL FUEL DEV CORP,TOKAI,IBARAKI,JAPAN
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中图分类号
T [工业技术];
学科分类号
08 ;
摘要
For better understanding of the behaviors of MgO and BaO within glass frit PF798, which is a candidate for use in immobilization of radioactive nuclear waste and consisted of 63.6SiO(2), 16.8 B2O3, 4.0Al(2)O(3), 3.0ZnO, 4.4CaO and 8.2Li(2)O in mole pet., oxidation-reduction equilibrium experiments for Fe3+/Fe2+ couple were conducted with the melts of {PF798 + MgO} and (PF798 + BaO) at 1473 K and under a stream of pure CO2 of 1 atm.
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页码:169 / 172
页数:4
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