catena-Poly[[[bis(1,10-phenanthroline-κ2N,N′)manganese(II)]-μ-2,2′-dithiodibenzoato-κ2O,O] methanol hemisolvate monohydrate]

被引：3

作者：

Zhou, Li-Ming ^{[1
]}

Zhang, Qiang ^{[1
]}

Hu, Min ^{[1
]}

机构：

[1] Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

COORDINATION POLYMER; PHOTOLUMINESCENCE; COMPLEXES;

D O I：

10.1107/S1600536809033388

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, {[Mn(C14H8O4S2)(C12H8N2)(2)]center dot 0.5CH(3)OH center dot-H2O}(n), has a one-dimensional chain structure in which the Mn-II atom is six-coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and two O atoms from two 2,2'-dithiodibenzoate (L) ligands. The L ligands adopt a bis(monodentate) (syn-anti) coordination mode and bridge adjacent Mn-II centres, generating a chain running along [201]. Adjacent chains are linked into a two-dimensional network, parallel to (10 (1) over bar), via interchain C-H center dot center dot center dot pi and pi-pi stacking [centroid-centroid distance = 3.477 (1) angstrom] interactions. The structure also contains numerous hydrogenbonding interactions, which further link the two-dimensional entities into a three-dimensional supramolecular network.

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收藏

页码：M1221 / +

页数：16

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