Preparation of benzylamine by highly selective reductive amination of benzaldehyde over Ru on an acidic activated carbon support as the catalyst

被引:36
作者
Gomez, S
Peters, JA
van der Waal, JC
Zhou, WZ
Maschmeyer, T
机构
[1] Delft Univ Technol, Lab Appl Organ Chem & Catalysis, DelftChemTech, NL-2628 BL Delft, Netherlands
[2] Avantium Technol BV, NL-1000 CX Amsterdam, Netherlands
[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
benzaldehyde; reductive amination; supported catalysts; ruthenium; selectivity;
D O I
10.1023/A:1021068432604
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ruthenium supported on activated carbon, on which acidic groups were introduced by pre-treatment with (NH(4))(2)S(2)O(8), is a highly active and selective catalyst for the synthesis of benzylamine via the reductive amination of benzaldehyde.
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页码:1 / 5
页数:5
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