SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE

被引：1

作者：

Kolybalov, D. S. ^{[1
]}

Sukhikh, T. S. ^{[1
]}

Bashirov, D. A. ^{[1
]}

Konchenko, S. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 62卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

coordination compounds; lanthanides; erbium; triazenes; synthesis; crystal structure; LANTHANIDE COMPLEXES; FORMAMIDINATE LIGANDS; EARTH; REACTIVITY; TRIAZENIDES; CHEMISTRY; EUROPIUM; BOND;

D O I：

10.1134/S0022476621020128

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By the interaction of [Er(N(SiMe3)(2))(3)] with HN(3)Dipp ((N(3)Dipp)(-) = N,N '-1,3-bis(2,6-diisopropylphenyl) triazenide) [Er(N(3)Dipp)(N(SiMe3)(2))(2)] (1) and [Er(N(3)Dipp)(2)(N(SiMe3)(2))] (2) complexes are obtained. The reaction of 2 with thiophenol gives [Er(N(3)Dipp)(2)(SPh)(THF)] complex (3). The structures of the compounds is determined by single crystal Xray diffraction of the following solid phases: 1, 2 center dot C6H6, and 3.

引用

页码：277 / 284

页数：8

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