POSS-Based Covalent Networks: Supporting and Stabilizing Pd for Heck Reaction in Aqueous Media

被引：25

作者：

Arsalani, Nasser ^{[1
]}

Akbari, Ali ^{[1
,3
]}

Amini, Mojtaba ^{[2
]}

Jabbari, Esmaiel ^{[3
]}

Gautam, Sanjeev ^{[4
]}

Chae, Keun Hwa ^{[5
]}

机构：

[1] Univ Tabriz, Dept Organ & Biochem, Res Lab Polymer, Fac Chem, POB 55666-16471, Tabriz, Iran

[2] Univ Maragheh, Dept Chem, Fac Sci, POB 55181-83111731, Maragheh, Iran

[3] Univ South Carolina, Dept Chem Engn, Columbia, SC 29208 USA

[4] Panjab Univ, Inst Chem Engn & Technol, Chandigarh 160014, India

[5] Korea Inst Sci & Technol, Adv Anal Ctr, Seoul 136791, South Korea

来源：

CATALYSIS LETTERS | 2017年 / 147卷 / 04期

关键词：

Polyhedral Oligomeric Silsesquioxane; Hybrid copolymer; Heck reaction; And radical polymerization; POLYHEDRAL OLIGOMERIC SILSESQUIOXANE; CATALYTIC-ACTIVITY; HYBRID NANOCOMPOSITES; MIZOROKI-HECK; SCHIFF-BASE; NANOPARTICLES; WATER; SONOGASHIRA; EPOXIDATION; COUPLINGS;

D O I：

10.1007/s10562-016-1954-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Palladium nanoparticles supported on Incompletely Condensed Polyhedral Oligomeric Silsesquioxane (IC-POSS) based poly (Acrylamide-co-Hydroxy ethyl methacrylate) as a novel nanohybrid catalyst were synthesized and characterized. This catalyst was found to be an efficient and reusable heterogeneous catalyst for the Heck reaction using water as the solvent in the absence of a phosphine ligand and phase transfer catalyst.

引用

页码：1086 / 1094

页数：9

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