The dissolution of a stationary spherical bubble beneath a flat plate

被引:21
作者
Kentish, Sandra [1 ]
Lee, Judy
Davidson, Malcolm
Ashokkumar, Muthupandian
机构
[1] Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia
[2] Univ Melbourne, Particulate Fluids Proc Ctr, Melbourne, Vic 3010, Australia
[3] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
基金
澳大利亚研究理事会;
关键词
single bubble; mass transfer; dissolution; diffusion coefficient;
D O I
10.1016/j.ces.2006.08.071
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The dissolution of a single stationary bubble held in place by a horizontal plate is commonly observed experimentally. For several decades the standard approach to the analysis of such dissolution data has been to apply a correction factor of ln(2) = 0.69 to the Epstein-Plesset equation for an isolated bubble. In this paper, the transport equations for a stationary bubble touching a plate are solved numerically for the common case where the flow field caused by the change in system volume as the bubble dissolves can be neglected. It is found that the total bubble lifetime is not well characterised by the use of the ln(2) factor. However, in most experimental situations, the initial stages of bubble dissolution are not captured. For low gas solubilities the use of a correction factor of 0.69 to the Epstein-Plesset equation is appropriate once the initial transients have dissipated. The correction factor varies from 0.69 to 0.77 across the full range of situations described in this paper. The mathematical model is validated by comparison to experimental data. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7697 / 7705
页数:9
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