Influence of the structures of hydrogen-bonded dimeric molecules on their adsorption at graphitized thermal carbon

被引：2

作者：

Kuznetsova, E. S. ^{[1
]}

Ul'yanov, A. V. ^{[1
]}

Buryak, A. K. ^{[1
]}

机构：

[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Moscow 119991, Russia

来源：

PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES | 2009年 / 45卷 / 04期

基金：

中国国家自然科学基金;

关键词：

AB-INITIO; ACID;

D O I：

10.1134/S207020510904008X

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

This study is devoted to the influence of the structures of hydrogen-bonded dimeric molecules on their adsorption at graphitized thermal carbon (GTC). The thermodynamic adsorption characteristics (TACs) of amino acid dimers and dimers of amino acids with acetic acid and formamide at GTC were determined. The results obtained for the adsorption of dimeric molecules at the carbon sorbent were compared with the calculated data for the molecules of the corresponding amino acids at GTC. The geometric parameters of dimeric molecules were varied to analyze the influence of the hydrogen bond lengths on the TACs of the compounds under study.

引用

页码：425 / 430

页数：6

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