Acceleration of the photocatalytic degradation of organics by in-situ removal of the products of degradation

被引:57
作者
Deepracha, Siwada [1 ]
Ayral, Andre [2 ]
Ogawa, Makoto [1 ]
机构
[1] Vidyasirimedhi Inst Sci & Technol VISTEC, Sch Energy Sci & Engn, 555 Moo 1 Tumbol Payupnai, Amphoe Wangchan 21210, Rayong, Thailand
[2] Univ Montpellier, Inst Europeen Membranes, CNRS, UMR 5635,IEM,ENSAM, Montpellier, France
关键词
Photocatalyst; Titania; Degradation; Equilibrium shift; BARIUM-SULFATE SCALE; AZO-DYES; INORGANIC-IONS; AQUEOUS SUSPENSION; POROUS MATERIALS; TIO2; WATER; INHIBITION; OXIDATION; TITANIA;
D O I
10.1016/j.apcatb.2020.119705
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocatalytic degradation of sulphur containing organics in water was substantially accelerated by the in-situ removal of sulphur oxide species formed by the dye degradation as metal sulfate precipitates. The significant enhancement of the degradation of methylene blue (C16H18ClN3S) and acid yellow 42 (C32H24N8Na2O8S2), as examples of sulphur containing organics, was achieved when the reactions were conducted in the presence of alkaline earth cations (such as Ca2+, Sr2+, and Ba2+).
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页数:7
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