Ionic IPNs as Novel Candidates for Highly Conductive Solid Polymer Electrolytes

被引：54
作者：
Shaplov, Alexander S. [1 ]
Goujon, Laurent [2 ]
Vidal, Frederic [2 ]
Lozinskaya, Elena I. [1 ]
Meyer, Franck [2 ]
Malyshkina, Inna A. [3 ]
Chevrot, Claude [2 ]
Teyssie, Dominique [2 ]
Odinets, Irina L. [1 ]
Vygodskii, Yakov S. [1 ]
机构：
[1] Russian Acad Sci INEOS RAS, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] Univ Cergy Pontoise, Lab Physicochim Polymeres & Interfaces, F-95031 Cergy Pontoise, France
[3] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119992, Russia
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2009年 / 47卷 / 17期
关键词：
conducting polymers; interpenetrating polymer networks (IPN); ionic liquids; ionomers; polyelectrolytes; polymer electrolytes; TEMPERATURE MOLTEN-SALTS; VINYL MONOMERS; RADICAL POLYMERIZATION; POLY(METHYL METHACRYLATE); DICYANAMIDE ANION; GEL ELECTROLYTES; LIQUIDS; IMIDAZOLIUM; NETWORKS; TETRAFLUOROBORATE;
D O I：
10.1002/pola.23478
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Five ionic imidazolium based monomers, namely 1-vinyl-3-ethylimidazolium bis(trifluoromethylsulfonyl)imide (ILM1), 1-vinyl-3-(diethoxyphosphinyl)-propylimidazolium bis(trifluoromethylsulfonyl)imide (ILM2), 1-[2-(2-methyl-acryloyloxy)-propyl]-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (ILM3), 1-[2-(2-methyl-acryloyloxy)-undecyl]-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (ILM4)), 1-vinyl-3-ethylimidazolium dicyanamide (ILM5) were prepared and used for the synthesis of linear polymeric ionic liquids (PILs), crosslinked networks with polyethyleneglycol dimethacrylate (PEGDM) and interpenetrating polymer networks (IPNs) based on polybutadiene (PB). The ionic conductivities of IPNs prepared using an in situ strategy were found to depend on the ILM nature, T-g and the ratio of the other components. Novel ionic IPNs are characterized by increased flexibility, small swelling ability in ionic liquids (ILs) along with high conductivity and preservation of mechanical stability even in a swollen state. The maximum conductivity for a pure IPN was equal to 3.6 x 10(-5) S/cm at 20 degrees C while for IPN swollen in [1-Me-3-Etim] 10(-2) (CN)(2)N sigma reached 8.5 x 10(-3) S/cm at 20 degrees C or 1.4 x S/cm at 50 degrees C. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4245-4266, 2009
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页码：4245 / 4266
页数：22
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