A novel method for the synthesis of solvent-free Mg(B3H8)2

被引：31

作者：

Huang, Jianmei ^{[1
,2
,3
,4
]}

Yan, Yigang ^{[4
]}

Remhof, Arndt ^{[4
]}

Zhang, Yucheng ^{[4
]}

Rentsch, Daniel ^{[4
]}

Au, Yuen S. ^{[5
]}

de Jongh, Petra E. ^{[5
]}

Cuevas, Fermin ^{[6
]}

Ouyang, Liuzhang ^{[1
,2
]}

Zhu, Min ^{[1
,2
]}

Zuettel, Andreas ^{[3
,4
]}

机构：

[1] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China

[2] S China Univ Technol, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510641, Guangdong, Peoples R China

[3] Ecole Polytech Fed Lausanne EPFL Valais Wallis, Inst Chem Sci & Engn ISIC, Energypolis, CH-1950 Sion, Switzerland

[4] Empa Swiss Fed Labs Mat Sci & Technol, CH-8600 Dubendorf, Switzerland

[5] Univ Utrecht, Debye Inst Nanomat Sci, Inorgan Chem & Catalysis, Univ Weg 99, NL-3584 CG Utrecht, Netherlands

[6] CMTR ICMPE CNRS UMR 7182, 2-8 Rue Henri Dunant, F-94320 Thiais, France

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 09期

基金：

对外科技合作项目（国际科技项目）; 瑞士国家科学基金会; 中国国家自然科学基金;

关键词：

SODIUM OCTAHYDROTRIBORATE; REVERSIBLE HYDROGENATION; CVD PRECURSORS; MAGNESIUM; NAB3H8; DECOMPOSITION; MG(BH4)(2); COMPLEXES; RELEASE; MG2NIH4;

D O I：

10.1039/c5dt04517g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This communication presents a novel and solvent-free method to synthesise Mg(B3H8)(2) via the gas-solid reaction between B2H6 and Mg2NiH4, which overcomes the limitations of wet chemical methods requiring solvent removal.

引用

页码：3687 / 3690

页数：4

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