Vacuum ultraviolet optical properties of MO-Y2O3-B2O3:Re (M = Mg,Sr; Re=Eu,Tb,Ce,Gd)

被引:5
作者
Zhou, Dan [1 ]
He, Dawei [1 ]
Liang, Zhongyi [1 ]
Hou, Tao [1 ]
机构
[1] Beijing Jiaotong Univ, Inst Optoelect Technol, Minist Educ, Key Lab Luminescence & Opt Informat, Beijing 100044, Peoples R China
关键词
phosphors; vacuum-ultraviolet (VUV); energy transfer;
D O I
10.1016/j.jlumin.2006.01.348
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
A series of phosphors MO-Re2O3-B2O3:Eu3+ (M = Mg,Sr; Re = Eu,Tb,Ce,Gd) were prepared and studied. Excitation spectra indicated a high absorption in vacuum ultraviolet (VUV) region. Strong emissions peaked at 591 and 613 nm, which were corresponding to the D-5(0) -> F-7(J) (J = 1, 2, 3, 4) transition of Eu3+ when excited under VUV. In addition to the host absorption band of MgO-Y2O3-B2O3, absorption bands around 172, 178, 195, 204 225 nm, were found which were corresponding to the 4f(8)-4f(7)5d transition of Tb3+ of MgO-Y2O3-B2O3:Re (Ce,Tb,Gd). Their energy transfer (Gd3+-Tb3+) was further discussed. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:993 / 996
页数:4
相关论文
共 5 条
  • [1] CHARGE-TRANSFER ABSORPTION-BAND OF EU3+ IN OXIDES
    HOEFDRAAD, HE
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1975, 15 (02) : 175 - 177
  • [2] Irradiation effects in LiF:Eu+3
    Kristianpoller, N
    Shmilevich, A
    Weiss, D
    Chen, R
    [J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2000, 166 : 556 - 560
  • [3] The lowest 4f-to-5d and charge-transfer transitions of rare earth ions in YPO4 hosts
    Nakazawa, E
    [J]. JOURNAL OF LUMINESCENCE, 2002, 100 (1-4) : 89 - 96
  • [4] VUV excitation of Y3Al5O12:: Tb phosphor prepared by a sol-gel process
    Park, CH
    Park, SJ
    Yu, BY
    Bae, HS
    Kim, CH
    Pyun, CH
    Guang-Yan, H
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 2000, 19 (04) : 335 - 338
  • [5] Wu XY, 2002, MATER RES BULL, V37, P1531, DOI 10.1016/S0025-5408(02)00860-7