Photocycloaddition of cyanoethylenes onto 1,4-dihydro- and 1,4,5,6-tetrahydro-pyridines

被引：5

作者：

Donati, D ^{[1
]}

Fusi, S ^{[1
]}

Ponticelli, F ^{[1
]}

机构：

[1] UNIV SIENA, IST CHIM ORGAN, I-53100 SIENA, ITALY

来源：

JOURNAL OF CHEMICAL RESEARCH | 1997年 / 02期

关键词：

D O I：

10.1039/a605331i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photochemical cycloaddition of cyanoethylenes onto the title compounds to give 2-azabicyclo[4.2.0] octanes shows a different degree of selectivity depending on the position of the chiral centre of the starting material, with a maximum effect in the case of the 4-position.

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页码：34 / +

相关论文

共 9 条

[1] ACRYLONITRILE PHOTOADDITION ON 1-BENZYL-1,4-DIHYDRONICOTINAMIDE [J].

ADEMBRI, G ;

DONATI, D ;

FUSI, S ;

PONTICELLI, F .

HETEROCYCLES, 1985, 23 (11) :2885-2889

[2] 2-AZABICYCLO[4.2.0]OCTANE DERIVATIVES - STEREOSELECTIVE PHOTOCHEMICAL-SYNTHESIS AND CHEMICAL-REACTIVITY [J].

ADEMBRI, G ;

DONATI, D ;

FUSI, S ;

PONTICELLI, F .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (15) :2033-2038

[3] PHOTOCHEMICAL ROUTE TO CYCLOBUT[B]ISOXAZOLO[4,5-E]PYRIDINE, A NEW HETEROCYCLIC SYSTEM [J].

ADEMBRI, G ;

DONATI, D ;

FUSI, S ;

PONTICELLI, F .

HETEROCYCLES, 1987, 26 (12) :3221-3227

[4]

DONATI D, 1994, GAZZ CHIM ITAL, V124, P71

[5] STRUCTURE OF ETHYL (3ARS,4ASR,5RS,6ASR,7ASR)-7-BENZYL-3-(PARA-CHLOROPHENYL)-6-CYANO-3A,4,4A,5,6,6A,7,7A-OCTAHYDROCYCLOBUT[B]ISOXAZOLO[4,5-E]PYRIDINE-4A-CARBOXYLATE - A NEW HETEROCYCLIC SYSTEM [J].

DONATI, D ;

FUSI, S ;

PONTICELLI, F ;

FIORENZA, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :317-319

[6]

KAGAN HB, 1967, STEREOCHEMISTRY, V1, P84

[7] REDUCTION BY A MODEL OF NAD(P)H - EFFECT OF METAL-ION AND STEREOCHEMISTRY ON REDUCTION OF ALPHA-KETO ESTERS BY 1,4-DIHYDRONICOTINAMIDE DERIVATIVES [J].

OHNISHI, Y ;

KAGAMI, M ;

OHNO, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (16) :4766-4768

[8]

PAASIVIRTA J, 1986, LANTHANIDE SHIFT REA, P119

[9]

SHING TL, 1991, SYNTHESIS-STUTTGART, P849