Clerodane diterpenes from Baccharis sagittalis:: insect antifeedant activity

被引:53
作者
Cifuente, DA [1 ]
Borkowski, EJ [1 ]
Sosa, ME [1 ]
Gianello, JC [1 ]
Giordano, OS [1 ]
Tonn, CE [1 ]
机构
[1] Univ Nacl San Luis, INTEQUI, CONICET, Fac Quim Bioquim & Farm, RA-5700 San Luis, Argentina
关键词
Baccharis sagittalis; Asteraceae; clerodane-type glycosides; beta-D-galactopyranosides; marrubiagenine; Tenebrio molitor L; insect antifeedant; structure-activity relationships;
D O I
10.1016/S0031-9422(02)00437-5
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Two clerodane-type diterpene glycosides esters, which were studied as peracetyl derivatives, together with the known diterpene marrubiagenine, were isolated from the aerial part of Baccharis sagittalis (Less). Their structures were established by spectroscopic methods. Antifeedant activity toward Tenebrio molitor larvae of the isolated compounds along with six other diterpenes was evaluated and some structure-antifeedant bioactivity relationships are reported. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:899 / 905
页数:7
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