Open versus Interpenetrated: Switchable Supramolecular Trajectories in Mechanosynthesis of a Halogen-Bonded Borromean Network

被引：17

作者：

Catalano, Luca ^{[1
]}

Germann, Luzia S. ^{[2
,3
]}

Julien, Patrick A. ^{[3
]}

Arhangelskis, Mihails ^{[4
]}

Halasz, Ivan ^{[5
]}

Uzarevic, Krunoslav ^{[5
]}

Etter, Martin ^{[6
]}

Dinnebier, Robert E. ^{[2
]}

Ursini, Maurizio ^{[1
]}

Cametti, Massimo ^{[1
]}

Marti-Rujas, Javier ^{[1
]}

Friscic, Tomislav ^{[3
,5
]}

Metrangolo, Pierangelo ^{[1
]}

Resnati, Giuseppe ^{[1
]}

Terraneo, Giancarlo ^{[1
]}

机构：

[1] Politecn Milan, Dept Chem Mat & Chem Engn Giulio Natta, Via L Mancinelli 7, I-20131 Milan, Italy

[2] Max Planck Inst Solid State Res, Heisenbergstr 1, Stuttgart, Germany

[3] McGill Univ, Dept Chem, 901 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada

[4] Univ Warsaw, Fac Chem, 1 Pasteura St, PL-02093 Warsaw, Poland

[5] Rudjer Boskovic Inst, Bijenicka 54, Zagreb 10000, Croatia

[6] DESY, D-22607 Hamburg, Germany

来源：

CHEM | 2021年 / 7卷 / 01期

基金：

欧洲研究理事会; 加拿大自然科学与工程研究理事会;

关键词：

IN-SITU; REAL-TIME; MECHANOCHEMICAL REACTIONS; RINGS; TOPOLOGY; DRIVEN;

D O I：

10.1016/j.chempr.2020.10.022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Precise control over topologically intricate molecular architectures remains an open challenge for chemists due to their inherent structural complexity, We report a simple solvent-free strategy to selectively prepare two multi-component supramolecular crystalline systems based on the halogen bond, endowed with either an unknot topology or a Borromean-type entanglement. Real-time In situ monitoring of the solvent-free mechanochemical synthesis of these three-component halogen-bonded ionic co-crystals reveals that the choice of milling conditions leads to a switch in the supramolecular reaction trajectory, resulting in the selective formation of an open halogen-bonded network or a halogen-bonded Borromean-type assembly.

引用

页码：146 / 154

页数：9

共 35 条

[31] Thorp-Greenwood FL, 2015, NAT CHEM, V7, P526, DOI [10.1038/NCHEM.2259, 10.1038/nchem.2259]
[32] Accurate Molecular Van Der Waals Interactions from Ground-State Electron Density and Free-Atom Reference Data
Tkatchenko, Alexandre
Scheffler, Matthias
[J]. PHYSICAL REVIEW LETTERS, 2009, 102 (07)
[33] Enthalpy vs. friction: heat flow modelling of unexpected temperature profiles in mechanochemistry of metal-organic frameworks
Uzarevic, Krunoslav
Ferdelji, Nenad
Mrla, Tomislav
Julien, Patrick A.
Halasz, Boris
Friscic, Tomislav
Halasz, Ivan
[J]. CHEMICAL SCIENCE, 2018, 9 (09) : 2525 - 2532
[34] Real-Time and In Situ Monitoring of Mechanochemical Reactions: A New Playground for All Chemists
Uzarevic, Krunoslav
Halasz, Ivan
Friscic, Tomislav
[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (20): : 4129 - 4140
[35] Self-Sorting Assembly of Molecular Trefoil Knots of Single Handedness
Zhong, Jiankang
Zhang, Liang
August, David P.
Whitehead, George F. S.
Leigh, David A.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (36) : 14249 - 14256

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