Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N-(2-hydroxybenzylidene) aniline

被引：2

作者：

Guillaume, Kodjo Charles ^{[1
]}

Herve, Zabri ^{[1
]}

Anoubile, Benie ^{[1
]}

Jacques, Estienne ^{[2
]}

机构：

[1] Univ Abobo Adjame, UFR SFA, Lab Chim Bioorgan & Subst Nat, Abidjan 02, Cote Ivoire

[2] Univ Aix Marseille 3, Lab Spectrometries & Physicochim Struct, Ctr St Jerome, F-13397 Marseille 20, France

来源：

E-JOURNAL OF CHEMISTRY | 2009年 / 6卷 / 04期

关键词：

Salicylideneaniline; X-ray structure; CH/Pi hydrogen bound; Thermochromic; photochromic; TOPOCHEMISTRY;

D O I：

10.1155/2009/473124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3,4,5-Trimethoxy N-(salicylidene) aniline was synthesized and characterized by IR spectroscopy, H-1 NMR and x-ray single crystal analysis. UV-visible spectroscopy was used for physicochemical tests. X-ray data reveals that the crystalline network cohesion of this compound is essentially assured by CH/pi type hydrogen bounds. It crystallized in the orthorhombic Pbcn space group. Electronic spectroscopy shows that the title compound doesn't present photochromic property but thermochromic one. Intermolecular interactions analysis confirms for this compound a thermochromic structural predisposition.

引用

页码：1103 / 1108

页数：6

共 13 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] TOPOCHEMISTRY .10. CRYSTAL + MOLECULAR STRUCTURES OF 2-CHLORO-N-SALICYLIDENEANILINE
BREGMAN, J
LEISEROW.L
OSAKI, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN): : 2086 - &
[3] TOPOCHEMISTRY .6. EXPERIMENTS ON PHOTOCHROMY + THERMOCHROMY OF CRYSTALLINE ANILS OF SALICYLALDEHYDES
COHEN, MD
SCHMIDT, GMJ
FLAVIAN, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN): : 2041 - &
[4] FERRARO A, 2000, THESIS BORDEAUX 1 U
[5] KITAIGOROSKI AI, 1973, MOL CRYSTALS MOL
[6] KODJO CG, 2008, PHYS CHEM NEWS, V39, P121
[7] KODJO CG, 1997, THESIS PROVENCE U MA
[8] UNUSUAL HOST-GUEST PI-ARENE ... H-BONDING IN A HOODED CAVITAND - THE FIRST SOLID-STATE STRUCTURE OF A CALIX[4]RESORCINARENE WITH UNDERIVATIZED HYDROXY-GROUPS
LEIGH, DA
LINNANE, P
PRITCHARD, RG
JACKSON, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) : 389 - 390
[9] MANSILLAKOBLAVI F, 1993, THESIS COCODY U ABID
[10] CRYSTAL-STRUCTURE OF THE INCLUSION COMPLEX OF BETA-CYCLODEXTRIN WITH 3,3-DIMETHYLBUTYLAMINE
MOUSTAKALIMAVRIDIS, I
HADJOUDIS, E
TSOUCARIS, G
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1990, 186 : 185 - 188

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